The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions
Тип публикации: Journal Article
Дата публикации: 2012-01-27
scimago Q1
Tоп 10% SciMago
wos Q1
white level БС1
SJR: 5.495
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
22287485
General Chemistry
Catalysis
Краткое описание
Palladium-catalyzed cross-coupling reactions enable organic chemists to form C-C bonds in targeted positions and under mild conditions. Although phosphine ligands have been intensively researched, in the search for even better cross-coupling catalysts attention has recently turned to the use of N-heterocyclic carbene (NHC) ligands, which form a strong bond to the palladium center. PEPPSI (pyridine-enhanced precatalyst preparation, stabilization, and initiation) palladium precatalysts with bulky NHC ligands have established themselves as successful alternatives to palladium phosphine complexes. This Review shows the success of these species in Suzuki-Miyaura, Negishi, and Stille-Migita cross-couplings as well as in amination and sulfination reactions.
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Valente C. et al. The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 14. pp. 3314-3332.
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Valente C., Çalimsiz S., Hoi K. H., Mallik D., Sayah M., Organ M. The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 14. pp. 3314-3332.
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TY - JOUR
DO - 10.1002/anie.201106131
UR - https://doi.org/10.1002/anie.201106131
TI - The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions
T2 - Angewandte Chemie - International Edition
AU - Valente, Cory
AU - Çalimsiz, Selçuk
AU - Hoi, Ka Hou
AU - Mallik, Debasis
AU - Sayah, Mahmoud
AU - Organ, Michael
PY - 2012
DA - 2012/01/27
PB - Wiley
SP - 3314-3332
IS - 14
VL - 51
PMID - 22287485
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2012_Valente,
author = {Cory Valente and Selçuk Çalimsiz and Ka Hou Hoi and Debasis Mallik and Mahmoud Sayah and Michael Organ},
title = {The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions},
journal = {Angewandte Chemie - International Edition},
year = {2012},
volume = {51},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201106131},
number = {14},
pages = {3314--3332},
doi = {10.1002/anie.201106131}
}
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Valente, Cory, et al. “The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions.” Angewandte Chemie - International Edition, vol. 51, no. 14, Jan. 2012, pp. 3314-3332. https://doi.org/10.1002/anie.201106131.
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