Angewandte Chemie - International Edition, volume 51, issue 31, pages 7830-7834
Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides
Publication type: Journal Article
Publication date: 2012-06-26
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
It takes alkynes! Exposure of propargyl chlorides to primary benzylic alcohols in the presence of [Ir(cod){(R)-segphos}]OTf (cod = 1,5-cyclooctadiene, segphos = 5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, Tf = trifluoromethanesulfonyl) results in hydrogen exchange to give allenyliridium-aldehyde pairs that combine to form products of propargylation with high ee value (see scheme). The reaction can also be conducted using aldehydes.
Found
Found
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Journal of the American Chemical Society
7 publications, 14.89%
|
|
|
Angewandte Chemie - International Edition
4 publications, 8.51%
|
|
|
Angewandte Chemie
4 publications, 8.51%
|
|
|
Organic Letters
3 publications, 6.38%
|
|
|
Chemistry - A European Journal
2 publications, 4.26%
|
|
|
Advanced Synthesis and Catalysis
2 publications, 4.26%
|
|
|
Chemical Reviews
2 publications, 4.26%
|
|
|
ACS Catalysis
2 publications, 4.26%
|
|
|
Chinese Journal of Organic Chemistry
1 publication, 2.13%
|
|
|
Journal of Organometallic Chemistry
1 publication, 2.13%
|
|
|
Asian Journal of Organic Chemistry
1 publication, 2.13%
|
|
|
ChemCatChem
1 publication, 2.13%
|
|
|
ChemInform
1 publication, 2.13%
|
|
|
European Journal of Organic Chemistry
1 publication, 2.13%
|
|
|
Journal of Organic Chemistry
1 publication, 2.13%
|
|
|
Accounts of Chemical Research
1 publication, 2.13%
|
|
|
Organometallics
1 publication, 2.13%
|
|
|
Chemical Science
1 publication, 2.13%
|
|
|
Annual Reports Section A (Inorganic Chemistry)
1 publication, 2.13%
|
|
|
Dalton Transactions
1 publication, 2.13%
|
|
|
Chemical Communications
1 publication, 2.13%
|
|
|
New Journal of Chemistry
1 publication, 2.13%
|
|
|
Nature Communications
1 publication, 2.13%
|
|
|
Synlett
1 publication, 2.13%
|
|
|
Russian Chemical Reviews
1 publication, 2.13%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
2
4
6
8
10
12
14
16
18
|
|
|
Wiley
18 publications, 38.3%
|
|
|
American Chemical Society (ACS)
17 publications, 36.17%
|
|
|
Royal Society of Chemistry (RSC)
5 publications, 10.64%
|
|
|
Elsevier
3 publications, 6.38%
|
|
|
Shanghai Institute of Organic Chemistry
1 publication, 2.13%
|
|
|
Springer Nature
1 publication, 2.13%
|
|
|
Georg Thieme Verlag KG
1 publication, 2.13%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.13%
|
|
|
2
4
6
8
10
12
14
16
18
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Woo S. K., Geary L. M., Krische M. J. Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 31. pp. 7830-7834.
GOST all authors (up to 50)
Copy
Woo S. K., Geary L. M., Krische M. J. Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 31. pp. 7830-7834.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201203334
UR - https://doi.org/10.1002/anie.201203334
TI - Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides
T2 - Angewandte Chemie - International Edition
AU - Woo, Sang Kook
AU - Geary, Laina M.
AU - Krische, Michael J
PY - 2012
DA - 2012/06/26
PB - Wiley
SP - 7830-7834
IS - 31
VL - 51
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Woo,
author = {Sang Kook Woo and Laina M. Geary and Michael J Krische},
title = {Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides},
journal = {Angewandte Chemie - International Edition},
year = {2012},
volume = {51},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/anie.201203334},
number = {31},
pages = {7830--7834},
doi = {10.1002/anie.201203334}
}
Cite this
MLA
Copy
Woo, Sang Kook, et al. “Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides.” Angewandte Chemie - International Edition, vol. 51, no. 31, Jun. 2012, pp. 7830-7834. https://doi.org/10.1002/anie.201203334.