Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps
Тип публикации: Journal Article
Дата публикации: 2013-01-23
scimago Q1
wos Q1
БС1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
23345201
General Chemistry
Catalysis
Краткое описание
On the right path: Based on DFT calculations (incorporating the role of water solvation) of the activation barriers of elementary steps, a new path that leads to methane and ethylene for CO2 electroreduction on Cu(111) was identified. Methane formation proceeds through reduction of CO to COH (path II, see picture), which leads to CHx species that can produce both methane and ethylene, as observed experimentally.
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855
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855
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MLA
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ГОСТ
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Nie X. et al. Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps // Angewandte Chemie - International Edition. 2013. Vol. 52. No. 9. pp. 2459-2462.
ГОСТ со всеми авторами (до 50)
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Nie X., Esopi M. R., Janik M. J., Asthagiri A. Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps // Angewandte Chemie - International Edition. 2013. Vol. 52. No. 9. pp. 2459-2462.
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RIS
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TY - JOUR
DO - 10.1002/anie.201208320
UR - https://doi.org/10.1002/anie.201208320
TI - Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps
T2 - Angewandte Chemie - International Edition
AU - Nie, Xiaowa
AU - Esopi, Monica R
AU - Janik, Michael John
AU - Asthagiri, Aravind
PY - 2013
DA - 2013/01/23
PB - Wiley
SP - 2459-2462
IS - 9
VL - 52
PMID - 23345201
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (до 50 авторов)
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@article{2013_Nie,
author = {Xiaowa Nie and Monica R Esopi and Michael John Janik and Aravind Asthagiri},
title = {Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps},
journal = {Angewandte Chemie - International Edition},
year = {2013},
volume = {52},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201208320},
number = {9},
pages = {2459--2462},
doi = {10.1002/anie.201208320}
}
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MLA
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Nie, Xiaowa, et al. “Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps.” Angewandte Chemie - International Edition, vol. 52, no. 9, Jan. 2013, pp. 2459-2462. https://doi.org/10.1002/anie.201208320.