Angewandte Chemie - International Edition, volume 52, issue 44, pages 11594-11598
Asymmetric Copolymerization of CO2withmeso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity
Publication type: Journal Article
Publication date: 2013-09-09
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Unprecedented enantioselectivity and catalytic activity was observed in the asymmetric copolymerization of CO2 with meso-epoxides (including the less reactive cyclopentene oxide) mediated by the dinuclear Co(III) complex (S,S,S,S)-1 under mild conditions. The resultant copolymers possess more than 99 % carbonate linkages and a perfectly isotactic structure.
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Liu Y. et al. Asymmetric Copolymerization of CO2withmeso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity // Angewandte Chemie - International Edition. 2013. Vol. 52. No. 44. pp. 11594-11598.
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Liu Y., Ren W., Liu J., Lu X. Asymmetric Copolymerization of CO2withmeso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity // Angewandte Chemie - International Edition. 2013. Vol. 52. No. 44. pp. 11594-11598.
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TY - JOUR
DO - 10.1002/anie.201305154
UR - https://doi.org/10.1002/anie.201305154
TI - Asymmetric Copolymerization of CO2withmeso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity
T2 - Angewandte Chemie - International Edition
AU - Liu, Ye
AU - Ren, Wei-Min
AU - Liu, Jie
AU - Lu, Xiao-Bing
PY - 2013
DA - 2013/09/09
PB - Wiley
SP - 11594-11598
IS - 44
VL - 52
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Liu,
author = {Ye Liu and Wei-Min Ren and Jie Liu and Xiao-Bing Lu},
title = {Asymmetric Copolymerization of CO2withmeso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity},
journal = {Angewandte Chemie - International Edition},
year = {2013},
volume = {52},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.201305154},
number = {44},
pages = {11594--11598},
doi = {10.1002/anie.201305154}
}
Cite this
MLA
Copy
Liu, Ye, et al. “Asymmetric Copolymerization of CO2withmeso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity.” Angewandte Chemie - International Edition, vol. 52, no. 44, Sep. 2013, pp. 11594-11598. https://doi.org/10.1002/anie.201305154.