Angewandte Chemie - International Edition, volume 53, issue 6, pages 1607-1610
Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers
Publication type: Journal Article
Publication date: 2014-01-22
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
PubMed ID:
24453135
General Chemistry
Catalysis
Abstract
A novel chemoselective polymerization control yields predictable (co)polymer compositions from a mixture of monomers. Using a dizinc catalyst and a mixture of caprolactone, cyclohexene oxide, and carbon dioxide enables the selective preparation of either polyesters or polycarbonates or copoly(ester-carbonates). The selectivity depends on the nature of the zinc-oxygen functionality at the growing polymer chain end, and can be controlled by the addition of exogeneous switch reagents.
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Romain C., Williams C. Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 6. pp. 1607-1610.
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Romain C., Williams C. Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 6. pp. 1607-1610.
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TY - JOUR
DO - 10.1002/anie.201309575
UR - https://doi.org/10.1002/anie.201309575
TI - Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers
T2 - Angewandte Chemie - International Edition
AU - Romain, C
AU - Williams, Charlotte
PY - 2014
DA - 2014/01/22
PB - Wiley
SP - 1607-1610
IS - 6
VL - 53
PMID - 24453135
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2014_Romain,
author = {C Romain and Charlotte Williams},
title = {Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201309575},
number = {6},
pages = {1607--1610},
doi = {10.1002/anie.201309575}
}
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Romain, C., and Charlotte Williams. “Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers.” Angewandte Chemie - International Edition, vol. 53, no. 6, Jan. 2014, pp. 1607-1610. https://doi.org/10.1002/anie.201309575.