volume 53 issue 10 pages 2754-2758

α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles

Publication typeJournal Article
Publication date2014-02-02
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
α-Halo and pseudohalo ketones are used for the first time as C(sp(3))-based electrophiles in transition-metal-catalyzed C-H activation and as oxidized alkyne equivalents in Rh(III)-catalyzed redox-neutral annulations to generate diverse N-heterocycles. This transformation is efficient and scalable. Due to the mild reaction conditions, a variety of functional groups could be tolerated.
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Yu D., De Azambuja F., Glorius F. α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 10. pp. 2754-2758.
GOST all authors (up to 50) Copy
Yu D., De Azambuja F., Glorius F. α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 10. pp. 2754-2758.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.201310272
UR - https://doi.org/10.1002/anie.201310272
TI - α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles
T2 - Angewandte Chemie - International Edition
AU - Yu, Da-Gang
AU - De Azambuja, Francisco
AU - Glorius, Frank
PY - 2014
DA - 2014/02/02
PB - Wiley
SP - 2754-2758
IS - 10
VL - 53
PMID - 24488682
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Yu,
author = {Da-Gang Yu and Francisco De Azambuja and Frank Glorius},
title = {α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201310272},
number = {10},
pages = {2754--2758},
doi = {10.1002/anie.201310272}
}
MLA
Cite this
MLA Copy
Yu., Da-Gang, et al. “α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles.” Angewandte Chemie - International Edition, vol. 53, no. 10, Feb. 2014, pp. 2754-2758. https://doi.org/10.1002/anie.201310272.