Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance
Тип публикации: Journal Article
Дата публикации: 2014-03-05
scimago Q1
wos Q1
БС1
SJR: 5.3
CiteScore: 26.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
24596034
General Chemistry
Catalysis
Краткое описание
Modular 1,2,3-triazoles enabled iron-catalyzed CH arylations with broad scope. The novel triazole-based bidentate auxiliary is easily accessible in a highly modular fashion and allowed for user-friendly iron-catalyzed C(sp(2) )H functionalizations of arenes and alkenes with excellent chemo- and diastereoselectivities. The versatile iron catalyst also proved applicable for challenging C(sp(3) )H functionalizations, and proceeds by an organometallic mode of action. The triazole-assisted CH activation strategy occurred under remarkably mild reaction conditions, and the auxiliary was easily removed in a traceless fashion. Intriguingly, the triazole group proved superior to previously used auxiliaries.
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ГОСТ |
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BibTex |
MLA
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ГОСТ
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Gu Q. et al. Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 15. pp. 3868-3871.
ГОСТ со всеми авторами (до 50)
Скопировать
Gu Q., Al Mamari H. H., Graczyk K., Diers E., Ackermann L. Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 15. pp. 3868-3871.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1002/anie.201311024
UR - https://doi.org/10.1002/anie.201311024
TI - Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance
T2 - Angewandte Chemie - International Edition
AU - Gu, Qing
AU - Al Mamari, Hamad H
AU - Graczyk, Karolina
AU - Diers, Emelyne
AU - Ackermann, Lutz
PY - 2014
DA - 2014/03/05
PB - Wiley
SP - 3868-3871
IS - 15
VL - 53
PMID - 24596034
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (до 50 авторов)
Скопировать
@article{2014_Gu,
author = {Qing Gu and Hamad H Al Mamari and Karolina Graczyk and Emelyne Diers and Lutz Ackermann},
title = {Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201311024},
number = {15},
pages = {3868--3871},
doi = {10.1002/anie.201311024}
}
Цитировать
MLA
Скопировать
Gu, Qing, et al. “Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance.” Angewandte Chemie - International Edition, vol. 53, no. 15, Mar. 2014, pp. 3868-3871. https://doi.org/10.1002/anie.201311024.