Aryl formate as bifunctional reagent: applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO.
Publication type: Journal Article
Publication date: 2014-02-14
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
24677435
General Chemistry
Catalysis
Abstract
After decades of development, carbonylation reactions have become one of the most powerful tools in modern organic synthesis. However, the requirement of CO gas limits the applications of such reactions. Reported herein is a versatile and practical protocol for carbonylative reactions which rely on the cooperation of phenyl formate and nonaflate, and the generation of CO in situ. This protocol has a high functionalgroup tolerance and could be applied in carbonylations with C, N, and, O nucleophiles. The corresponding amides, alkynones, furanones, and aryl benzoates were synthesized in good yields.
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104
Total citations:
104
Citations from 2024:
14
(13.46%)
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GOST
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Li H. et al. Aryl formate as bifunctional reagent: applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO. // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 12. pp. 3183-3186.
GOST all authors (up to 50)
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Li H., Neumann H., Beller M., Wu X. Aryl formate as bifunctional reagent: applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO. // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 12. pp. 3183-3186.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201311198
UR - https://doi.org/10.1002/anie.201311198
TI - Aryl formate as bifunctional reagent: applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO.
T2 - Angewandte Chemie - International Edition
AU - Li, Haoquan
AU - Neumann, Helfried
AU - Beller, Matthias
AU - Wu, Xiao-Feng
PY - 2014
DA - 2014/02/14
PB - Wiley
SP - 3183-3186
IS - 12
VL - 53
PMID - 24677435
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Li,
author = {Haoquan Li and Helfried Neumann and Matthias Beller and Xiao-Feng Wu},
title = {Aryl formate as bifunctional reagent: applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO.},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201311198},
number = {12},
pages = {3183--3186},
doi = {10.1002/anie.201311198}
}
Cite this
MLA
Copy
Li, Haoquan, et al. “Aryl formate as bifunctional reagent: applications in palladium-catalyzed carbonylative coupling reactions using in situ generated CO..” Angewandte Chemie - International Edition, vol. 53, no. 12, Feb. 2014, pp. 3183-3186. https://doi.org/10.1002/anie.201311198.