Angewandte Chemie - International Edition, volume 53, issue 17, pages 4350-4354
A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions
Publication type: Journal Article
Publication date: 2014-03-20
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
A simple, new type of chiral sulfinamide monophosphines, the so-called Ming-Phos ligands, is reported; these ligands could be easily prepared from inexpensive and commercially available starting materials. The Ming-Phos ligands performed well in the enantioselective gold-catalyzed cycloaddition reaction of 2-(1-alkynyl)-alk-2-en-1-ones with nitrones. Both enantiomers of the products could be obtained in good yields and with excellent diastereo- and enantioselectivity through transformations that were catalyzed by gold complexes derived from two diastereomers of Ming-Phos ligand M5 (Ar=1-naphthyl).
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Zhang Z. et al. A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 17. pp. 4350-4354.
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Zhang Z., Chen P., Li W., Niu Y., Zhao X., Zhang J. A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 17. pp. 4350-4354.
Cite this
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TY - JOUR
DO - 10.1002/anie.201401067
UR - https://doi.org/10.1002/anie.201401067
TI - A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions
T2 - Angewandte Chemie - International Edition
AU - Zhang, Zhan-Ming
AU - Chen, Peng
AU - Li, Wenbo
AU - Niu, Yanfei
AU - Zhao, Xiao-Li
AU - Zhang, Junliang
PY - 2014
DA - 2014/03/20
PB - Wiley
SP - 4350-4354
IS - 17
VL - 53
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2014_Zhang,
author = {Zhan-Ming Zhang and Peng Chen and Wenbo Li and Yanfei Niu and Xiao-Li Zhao and Junliang Zhang},
title = {A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201401067},
number = {17},
pages = {4350--4354},
doi = {10.1002/anie.201401067}
}
Cite this
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Zhang, Zhan-Ming, et al. “A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions.” Angewandte Chemie - International Edition, vol. 53, no. 17, Mar. 2014, pp. 4350-4354. https://doi.org/10.1002/anie.201401067.