Angewandte Chemie - International Edition, volume 53, issue 26, pages 6645-6649

Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles

Kai Chen ¹

Zi-Zhong Zhu ¹

YONG-SHENG ZHANG ²

Xiang-Ying Tang ²

Min Shi ^{3, 4, 5, 6}

Hide authors affiliations Show authors affiliations: 6 affiliations

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road No. 130, Shanghai, 200237, China. |

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 (China) |

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road No. 130, Shanghai, 200237 (China) |

⁴

State Key Laboratory of Organometallic Chemistry

⁵

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences |

⁶

345 Lingling Road Shanghai 200032 China |

Publication type: Journal Article

Publication date: 2014-05-18

Wiley

Journal: Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor: 16.6

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201402803

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General Chemistry

Catalysis

Abstract

The azavinyl rhodium carbenes derived from N-sulfonyltriazole methylenecyclopropanes were found to be very reactive in the divergent synthesis of N-containing heterocycles. Different types of cycloisomerizations were observed depending on the substrates. Derivatization of the products easily gave a series of diazabicyclo[3.2.1]octane derivatives. Bs=bromobenzenesulfonyl, Ms=methanesulfonyl, Piv=pivalate, Ts=4-toluenesulfonyl.

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Chen K. et al. Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 26. pp. 6645-6649.

GOST all authors (up to 50) Copy

Chen K., Zhu Z., ZHANG Y., Tang X., Shi M. Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 26. pp. 6645-6649.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201402803

UR - https://doi.org/10.1002/anie.201402803

TI - Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles

T2 - Angewandte Chemie - International Edition

AU - Chen, Kai

AU - Zhu, Zi-Zhong

AU - ZHANG, YONG-SHENG

AU - Tang, Xiang-Ying

AU - Shi, Min

PY - 2014

DA - 2014/05/18 00:00:00

PB - Wiley

SP - 6645-6649

IS - 26

VL - 53

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex Copy

@article{2014_Chen,

author = {Kai Chen and Zi-Zhong Zhu and YONG-SHENG ZHANG and Xiang-Ying Tang and Min Shi},

title = {Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles},

journal = {Angewandte Chemie - International Edition},

year = {2014},

volume = {53},

publisher = {Wiley},

month = {may},

url = {https://doi.org/10.1002/anie.201402803},

number = {26},

pages = {6645--6649},

doi = {10.1002/anie.201402803}

}

MLA

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MLA Copy

Chen, Kai, et al. “Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles.” Angewandte Chemie - International Edition, vol. 53, no. 26, May. 2014, pp. 6645-6649. https://doi.org/10.1002/anie.201402803.

Found error?

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor

16.6

ISSN

14337851 (Print)
15213773 (Electronic)