Angewandte Chemie - International Edition, volume 53, issue 26, pages 6645-6649
Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles
4
State Key Laboratory of Organometallic Chemistry
6
345 Lingling Road Shanghai 200032 China
|
Publication type: Journal Article
Publication date: 2014-05-18
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The azavinyl rhodium carbenes derived from N-sulfonyltriazole methylenecyclopropanes were found to be very reactive in the divergent synthesis of N-containing heterocycles. Different types of cycloisomerizations were observed depending on the substrates. Derivatization of the products easily gave a series of diazabicyclo[3.2.1]octane derivatives. Bs=bromobenzenesulfonyl, Ms=methanesulfonyl, Piv=pivalate, Ts=4-toluenesulfonyl.
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Chen K. et al. Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 26. pp. 6645-6649.
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Chen K., Zhu Z., ZHANG Y., Tang X., Shi M. Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 26. pp. 6645-6649.
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TY - JOUR
DO - 10.1002/anie.201402803
UR - https://doi.org/10.1002/anie.201402803
TI - Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles
T2 - Angewandte Chemie - International Edition
AU - Chen, Kai
AU - Zhu, Zi-Zhong
AU - ZHANG, YONG-SHENG
AU - Tang, Xiang-Ying
AU - Shi, Min
PY - 2014
DA - 2014/05/18
PB - Wiley
SP - 6645-6649
IS - 26
VL - 53
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2014_Chen,
author = {Kai Chen and Zi-Zhong Zhu and YONG-SHENG ZHANG and Xiang-Ying Tang and Min Shi},
title = {Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/anie.201402803},
number = {26},
pages = {6645--6649},
doi = {10.1002/anie.201402803}
}
Cite this
MLA
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Chen, Kai, et al. “Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles.” Angewandte Chemie - International Edition, vol. 53, no. 26, May. 2014, pp. 6645-6649. https://doi.org/10.1002/anie.201402803.