Angewandte Chemie - International Edition, volume 53, issue 32, pages 8492-8497
Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach
Publication type: Journal Article
Publication date: 2014-06-25
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
A novel Ru(0)- and Rh(I)-catalyzed noncarbonylative and carbonylative cycloisomerization of readily available 3-alkynyl imine derivatives has been developed to provide 3,4-fused or nonfused pyrrole derivatives efficiently in moderate to excellent yields. The key steps involve the formation of a ruthenium carbenoid intermediate or a rhodacycle intermediate, respectively. In these reactions, CO can serve as a ligand or a reagent.
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Chen G. Q. et al. Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 32. pp. 8492-8497.
GOST all authors (up to 50)
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Chen G. Q., Zhang X., Wei Yin 尹., Tang X., Shi M. Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach // Angewandte Chemie - International Edition. 2014. Vol. 53. No. 32. pp. 8492-8497.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201405215
UR - https://doi.org/10.1002/anie.201405215
TI - Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach
T2 - Angewandte Chemie - International Edition
AU - Chen, Gen Qiang
AU - Zhang, Xiao-Nan
AU - Wei Yin, 尹维
AU - Tang, Xiang-Ying
AU - Shi, Min
PY - 2014
DA - 2014/06/25
PB - Wiley
SP - 8492-8497
IS - 32
VL - 53
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2014_Chen,
author = {Gen Qiang Chen and Xiao-Nan Zhang and 尹维 Wei Yin and Xiang-Ying Tang and Min Shi},
title = {Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach},
journal = {Angewandte Chemie - International Edition},
year = {2014},
volume = {53},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/anie.201405215},
number = {32},
pages = {8492--8497},
doi = {10.1002/anie.201405215}
}
Cite this
MLA
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Chen, Gen Qiang, et al. “Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach.” Angewandte Chemie - International Edition, vol. 53, no. 32, Jun. 2014, pp. 8492-8497. https://doi.org/10.1002/anie.201405215.