Angewandte Chemie - International Edition

, volume 54 , issue 22 , pages 6400-6441

Frustrated Lewis Pair Chemistry: Development and Perspectives

Douglas W. Stephan ¹

Gerhard Erker ^{2, 3, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

Department of Chemistry, University of Toronto, 80 St. George St, Toronto, Ontario M5S3H6 (Canada). |

Organisch-Chemisches Institut

Westfälische Wilhelms-Universität |

⁴

Corrensstr. 40 48149 Münster Germany |

Publication type: Journal Article

Publication date: 2015-05-14

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201409800

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PubMed ID: 25974714

General Chemistry

Catalysis

Abstract

Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in solution that are deterred from strong adduct formation by steric and/or electronic factors. This opens pathways to novel cooperative reactions with added substrates. Small-molecule binding and activation by FLPs has led to the discovery of a variety of new reactions through unprecedented pathways. Hydrogen activation and subsequent manipulation in metal-free catalytic hydrogenations is a frequently observed feature of many FLPs. The current state of this young but rapidly expanding field is outlined in this Review and the future directions for its broadening sphere of impact are considered.

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Stephan D. W. et al. Frustrated Lewis Pair Chemistry: Development and Perspectives // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 22. pp. 6400-6441.

GOST all authors (up to 50) Copy

Stephan D. W., Erker G. Frustrated Lewis Pair Chemistry: Development and Perspectives // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 22. pp. 6400-6441.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201409800

UR - https://doi.org/10.1002/anie.201409800

TI - Frustrated Lewis Pair Chemistry: Development and Perspectives

T2 - Angewandte Chemie - International Edition

AU - Stephan, Douglas W.

AU - Erker, Gerhard

PY - 2015

DA - 2015/05/14

PB - Wiley

SP - 6400-6441

IS - 22

VL - 54

PMID - 25974714

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2015_Stephan,

author = {Douglas W. Stephan and Gerhard Erker},

title = {Frustrated Lewis Pair Chemistry: Development and Perspectives},

journal = {Angewandte Chemie - International Edition},

year = {2015},

volume = {54},

publisher = {Wiley},

month = {may},

url = {https://doi.org/10.1002/anie.201409800},

number = {22},

pages = {6400--6441},

doi = {10.1002/anie.201409800}

}

MLA

Cite this

MLA Copy

Stephan, Douglas W., et al. “Frustrated Lewis Pair Chemistry: Development and Perspectives.” Angewandte Chemie - International Edition, vol. 54, no. 22, May. 2015, pp. 6400-6441. https://doi.org/10.1002/anie.201409800.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)