Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes
Publication type: Journal Article
Publication date: 2015-02-16
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
25689682
General Chemistry
Catalysis
Abstract
A one-step procedure for the first radical CH arylation of BODIPY dyes has been developed. This method uses ferrocene [FeCp2] to generate aryl radical species from aryldiazonium salts and allows the synthesis of brightly fluorescent (Φ>0.85) 3,5-diarylated and 3-monoarylated boron dipyrrins in up to 86 % yield for a broad range of aryl substituents. In this way, new and complex dyes with red-shifted spectra can be easily prepared.
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132
Total citations:
132
Citations from 2024:
17
(12.88%)
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GOST
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Verbelen B. et al. Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 15. pp. 4612-4616.
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Verbelen B., Boodts S., Hofkens J., Boens N., Dehaen W. Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 15. pp. 4612-4616.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201410853
UR - https://doi.org/10.1002/anie.201410853
TI - Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes
T2 - Angewandte Chemie - International Edition
AU - Verbelen, Bram
AU - Boodts, Stijn
AU - Hofkens, J.
AU - Boens, Noël
AU - Dehaen, Wim
PY - 2015
DA - 2015/02/16
PB - Wiley
SP - 4612-4616
IS - 15
VL - 54
PMID - 25689682
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Verbelen,
author = {Bram Verbelen and Stijn Boodts and J. Hofkens and Noël Boens and Wim Dehaen},
title = {Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201410853},
number = {15},
pages = {4612--4616},
doi = {10.1002/anie.201410853}
}
Cite this
MLA
Copy
Verbelen, Bram, et al. “Radical CH Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes.” Angewandte Chemie - International Edition, vol. 54, no. 15, Feb. 2015, pp. 4612-4616. https://doi.org/10.1002/anie.201410853.