Structural Characterization of a Hydroperoxo Nickel Complex and Its Autoxidation: Mechanism of Interconversion between Peroxo, Superoxo, and Hydroperoxo Species
Publication type: Journal Article
Publication date: 2015-02-20
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
25704927
General Chemistry
Catalysis
Abstract
Pincer-stabilized nickel(I) complexes readily react with molecular oxygen to form dinuclear 1,2-μ-peroxo-bridged nickel(II) complexes, which are the major components of a dynamic equilibrium with the corresponding mononuclear superoxo species. The peroxo complexes further react with hydrogen peroxide to give the corresponding nickel(II) hydroperoxides. One of these hitherto elusive species was characterized by X-ray diffraction for the first time [O-O bond length: 1.492(2) Å].
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45
Total citations:
45
Citations from 2025:
2
(4.44%)
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Rettenmeier C. A., Wadepohl H., Gade L. Structural Characterization of a Hydroperoxo Nickel Complex and Its Autoxidation: Mechanism of Interconversion between Peroxo, Superoxo, and Hydroperoxo Species // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 16. pp. 4880-4884.
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Rettenmeier C. A., Wadepohl H., Gade L. Structural Characterization of a Hydroperoxo Nickel Complex and Its Autoxidation: Mechanism of Interconversion between Peroxo, Superoxo, and Hydroperoxo Species // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 16. pp. 4880-4884.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201500141
UR - https://doi.org/10.1002/anie.201500141
TI - Structural Characterization of a Hydroperoxo Nickel Complex and Its Autoxidation: Mechanism of Interconversion between Peroxo, Superoxo, and Hydroperoxo Species
T2 - Angewandte Chemie - International Edition
AU - Rettenmeier, Christoph A
AU - Wadepohl, Hubert
AU - Gade, Lutz
PY - 2015
DA - 2015/02/20
PB - Wiley
SP - 4880-4884
IS - 16
VL - 54
PMID - 25704927
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Rettenmeier,
author = {Christoph A Rettenmeier and Hubert Wadepohl and Lutz Gade},
title = {Structural Characterization of a Hydroperoxo Nickel Complex and Its Autoxidation: Mechanism of Interconversion between Peroxo, Superoxo, and Hydroperoxo Species},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201500141},
number = {16},
pages = {4880--4884},
doi = {10.1002/anie.201500141}
}
Cite this
MLA
Copy
Rettenmeier, Christoph A., et al. “Structural Characterization of a Hydroperoxo Nickel Complex and Its Autoxidation: Mechanism of Interconversion between Peroxo, Superoxo, and Hydroperoxo Species.” Angewandte Chemie - International Edition, vol. 54, no. 16, Feb. 2015, pp. 4880-4884. https://doi.org/10.1002/anie.201500141.