Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination
Publication type: Journal Article
Publication date: 2015-03-10
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
25757459
General Chemistry
Catalysis
Abstract
Ruthenium(II) complexes catalyze the CC coupling of 1,1-disubstituted allenes and fluorinated alcohols to form homoallylic alcohols bearing all-carbon quaternary centers with good to complete levels of diastereoselectivity. Whereas fluorinated alcohols are relatively abundant and tractable, the corresponding aldehydes are often not commercially available because of their instability.
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57
Total citations:
57
Citations from 2024:
7
(12%)
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Sam B., Luong T., Krische M. J. Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 18. pp. 5465-5469.
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Sam B., Luong T., Krische M. J. Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 18. pp. 5465-5469.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201500238
UR - https://doi.org/10.1002/anie.201500238
TI - Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination
T2 - Angewandte Chemie - International Edition
AU - Sam, Brannon
AU - Luong, Tom
AU - Krische, Michael J
PY - 2015
DA - 2015/03/10
PB - Wiley
SP - 5465-5469
IS - 18
VL - 54
PMID - 25757459
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Sam,
author = {Brannon Sam and Tom Luong and Michael J Krische},
title = {Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201500238},
number = {18},
pages = {5465--5469},
doi = {10.1002/anie.201500238}
}
Cite this
MLA
Copy
Sam, Brannon, et al. “Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination.” Angewandte Chemie - International Edition, vol. 54, no. 18, Mar. 2015, pp. 5465-5469. https://doi.org/10.1002/anie.201500238.