Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂.
Publication type: Journal Article
Publication date: 2015-04-07
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
25850597
General Chemistry
Catalysis
Abstract
A highly efficient catalyst system based on ruthenium-pincer-type complexes has been discovered for N-formylation of various amines with CO2 and H2, thus affording the corresponding formamides with excellent productivity (turnover numbers of up to 1,940,000 in a single batch) and selectivity. Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N-dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost-effective process. A one-pot two-step procedure for hydrogenation of CO2 to methanol via the intermediacy of formamide formation has also been developed.
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323
Total citations:
323
Citations from 2024:
52
(16.1%)
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GOST
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Zhang L. et al. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂. // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 21. pp. 6186-6189.
GOST all authors (up to 50)
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Zhang L., Han Z., Zhao X., Wang Z., Ding K. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂. // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 21. pp. 6186-6189.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201500939
UR - https://doi.org/10.1002/anie.201500939
TI - Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂.
T2 - Angewandte Chemie - International Edition
AU - Zhang, Lei
AU - Han, Zhaobin
AU - Zhao, Xiaoyu
AU - Wang, Zheng
AU - Ding, Kuiling
PY - 2015
DA - 2015/04/07
PB - Wiley
SP - 6186-6189
IS - 21
VL - 54
PMID - 25850597
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Zhang,
author = {Lei Zhang and Zhaobin Han and Xiaoyu Zhao and Zheng Wang and Kuiling Ding},
title = {Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂.},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201500939},
number = {21},
pages = {6186--6189},
doi = {10.1002/anie.201500939}
}
Cite this
MLA
Copy
Zhang, Lei, et al. “Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H₂ and CO₂..” Angewandte Chemie - International Edition, vol. 54, no. 21, Apr. 2015, pp. 6186-6189. https://doi.org/10.1002/anie.201500939.