Angewandte Chemie - International Edition, volume 54, issue 24, pages 7042-7046
Crystalline Hetero-Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures
Publication type: Journal Article
Publication date: 2015-04-27
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Stereocomplexation is the stereoselective interaction between two opposite enantiomeric polymers through an interlocked orderly assembly. Most studies focus on the stereocomplex formation from the crystalline opposite enantiomers having the identical structure; nevertheless, rare examples were reported regarding the crystalline stereocomplexes from enantiomeric polymers having different chemical structures. Herein we show a strategy for polymer orderly assembly through the formation of crystalline hetero-stereocomplexed polymeric materials by the cocrystallization of amorphous isotactic polycarbonates with different chemical structures and opposite configurations. The behaviors in the crystalline state are significantly different from that of the component enantiomeric polymers or their homo-stereocomplexes. This study is expected to open up a new way to prepare various semicrystalline materials having a wide variety of physical properties and degradability.
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Liu Y. et al. Crystalline Hetero-Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 24. pp. 7042-7046.
GOST all authors (up to 50)
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Liu Y., Wang M., Ren W., Xu Y., Lu X. Crystalline Hetero-Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 24. pp. 7042-7046.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201501417
UR - https://doi.org/10.1002/anie.201501417
TI - Crystalline Hetero-Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures
T2 - Angewandte Chemie - International Edition
AU - Liu, Ye
AU - Wang, Meng
AU - Ren, Wei-min
AU - Xu, Yue-Chao
AU - Lu, Xiao-Bing
PY - 2015
DA - 2015/04/27
PB - Wiley
SP - 7042-7046
IS - 24
VL - 54
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2015_Liu,
author = {Ye Liu and Meng Wang and Wei-min Ren and Yue-Chao Xu and Xiao-Bing Lu},
title = {Crystalline Hetero-Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201501417},
number = {24},
pages = {7042--7046},
doi = {10.1002/anie.201501417}
}
Cite this
MLA
Copy
Liu, Ye, et al. “Crystalline Hetero-Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures.” Angewandte Chemie - International Edition, vol. 54, no. 24, Apr. 2015, pp. 7042-7046. https://doi.org/10.1002/anie.201501417.