A Neutral Silicon/Phosphorus Frustrated Lewis Pair
Benedikt Waerder
1
,
Martin Pieper
1
,
Leif A Körte
1
,
Timo A Kinder
1
,
A Mix
1
,
Beate Neumann
1
,
Hans-Georg Stammler
1
,
Publication type: Journal Article
Publication date: 2015-11-02
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
26423202
General Chemistry
Catalysis
Abstract
Frustrated Lewis pairs (FLPs) have a great potential for activation of small molecules. Most known FLP systems are based on boron or aluminum atoms as acid functions, few on zinc, and only two on boron-isoelectronic silicenium cation systems. The first FLP system based on a neutral silane, (C2F5)3SiCH2P(tBu)2 (1), was prepared from (C2F5)3SiCl with C2F5 groups of very high electronegativity and LiCH2P(tBu)2. 1 is capable of cleaving hydrogen, and adds CO2 and SO2. Hydrogen splitting was confirmed by H/D scrambling reactions. The structures of 1, its CO2 and SO2 adducts, and a decomposition product with CO2 were elucidated by X-ray diffraction.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
16
18
|
|
|
Chemistry - A European Journal
18 publications, 19.78%
|
|
|
Dalton Transactions
9 publications, 9.89%
|
|
|
Angewandte Chemie - International Edition
7 publications, 7.69%
|
|
|
Angewandte Chemie
6 publications, 6.59%
|
|
|
European Journal of Inorganic Chemistry
6 publications, 6.59%
|
|
|
Chemical Communications
6 publications, 6.59%
|
|
|
Chemical Science
5 publications, 5.49%
|
|
|
Chemistry - An Asian Journal
4 publications, 4.4%
|
|
|
Inorganic Chemistry
4 publications, 4.4%
|
|
|
Organometallics
3 publications, 3.3%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
3 publications, 3.3%
|
|
|
Journal of Physical Chemistry A
3 publications, 3.3%
|
|
|
ChemistryEurope
3 publications, 3.3%
|
|
|
Progress in Reaction Kinetics and Mechanism
1 publication, 1.1%
|
|
|
Crystals
1 publication, 1.1%
|
|
|
Journal of Organometallic Chemistry
1 publication, 1.1%
|
|
|
Chinese Journal of Chemistry
1 publication, 1.1%
|
|
|
International Journal of Quantum Chemistry
1 publication, 1.1%
|
|
|
Macromolecules
1 publication, 1.1%
|
|
|
Journal of Physical Chemistry C
1 publication, 1.1%
|
|
|
Physical Chemistry Chemical Physics
1 publication, 1.1%
|
|
|
Mendeleev Communications
1 publication, 1.1%
|
|
|
Journal of Molecular Modeling
1 publication, 1.1%
|
|
|
Journal of the American Chemical Society
1 publication, 1.1%
|
|
|
2
4
6
8
10
12
14
16
18
|
Publishers
|
10
20
30
40
50
|
|
|
Wiley
50 publications, 54.95%
|
|
|
Royal Society of Chemistry (RSC)
21 publications, 23.08%
|
|
|
American Chemical Society (ACS)
13 publications, 14.29%
|
|
|
Elsevier
3 publications, 3.3%
|
|
|
SAGE
1 publication, 1.1%
|
|
|
MDPI
1 publication, 1.1%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 1.1%
|
|
|
Springer Nature
1 publication, 1.1%
|
|
|
10
20
30
40
50
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
91
Total citations:
91
Citations from 2025:
8
(8.79%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Waerder B. et al. A Neutral Silicon/Phosphorus Frustrated Lewis Pair // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 45. pp. 13416-13419.
GOST all authors (up to 50)
Copy
Waerder B., Pieper M., Körte L. A., Kinder T. A., Mix A., Neumann B., Stammler H., Mitzel N. W. A Neutral Silicon/Phosphorus Frustrated Lewis Pair // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 45. pp. 13416-13419.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201504171
UR - https://doi.org/10.1002/anie.201504171
TI - A Neutral Silicon/Phosphorus Frustrated Lewis Pair
T2 - Angewandte Chemie - International Edition
AU - Waerder, Benedikt
AU - Pieper, Martin
AU - Körte, Leif A
AU - Kinder, Timo A
AU - Mix, A
AU - Neumann, Beate
AU - Stammler, Hans-Georg
AU - Mitzel, Norbert Werner
PY - 2015
DA - 2015/11/02
PB - Wiley
SP - 13416-13419
IS - 45
VL - 54
PMID - 26423202
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Waerder,
author = {Benedikt Waerder and Martin Pieper and Leif A Körte and Timo A Kinder and A Mix and Beate Neumann and Hans-Georg Stammler and Norbert Werner Mitzel},
title = {A Neutral Silicon/Phosphorus Frustrated Lewis Pair},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/anie.201504171},
number = {45},
pages = {13416--13419},
doi = {10.1002/anie.201504171}
}
Cite this
MLA
Copy
Waerder, Benedikt, et al. “A Neutral Silicon/Phosphorus Frustrated Lewis Pair.” Angewandte Chemie - International Edition, vol. 54, no. 45, Nov. 2015, pp. 13416-13419. https://doi.org/10.1002/anie.201504171.