Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds
Vincent Corcé
1
,
Lise-Marie Chamoreau
1
,
Etienne Derat
1
,
Jean Philippe Goddard
1, 2
,
Cyril Ollivier
1
,
Louis Fensterbank
1
Publication type: Journal Article
Publication date: 2015-07-24
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
26216069
General Chemistry
Catalysis
Abstract
This works introduces hypervalent bis‐catecholato silicon compounds as versatile sources of alkyl radicals upon visible‐light photocatalysis. Using Ir[(dF(CF3)ppy)2(bpy)](PF6) (dF(CF3)ppy=2‐(2,4‐difluorophenyl)‐5‐trifluoromethylpyridine, bpy=bipyridine) as catalytic photooxidant, a series of alkyl radicals, including highly reactive primary ones can be generated and engaged in various intermolecular homolytic reactions. Based on cyclic voltammetry, Stern–Volmer studies, and supported by calculations, a mechanism involving a single‐electron transfer from the silicate to the photoactivated iridium complex has been proposed. This oxidative photocatalyzed process can be efficiently merged with nickel‐catalyzed C
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285
Total citations:
285
Citations from 2025:
23
(8.07%)
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GOST
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Corcé V. et al. Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 39. pp. 11414-11418.
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Corcé V., Chamoreau L., Derat E., Goddard J. P., Ollivier C., Fensterbank L. Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 39. pp. 11414-11418.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201504963
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201504963
TI - Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds
T2 - Angewandte Chemie - International Edition
AU - Corcé, Vincent
AU - Chamoreau, Lise-Marie
AU - Derat, Etienne
AU - Goddard, Jean Philippe
AU - Ollivier, Cyril
AU - Fensterbank, Louis
PY - 2015
DA - 2015/07/24
PB - Wiley
SP - 11414-11418
IS - 39
VL - 54
PMID - 26216069
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Corcé,
author = {Vincent Corcé and Lise-Marie Chamoreau and Etienne Derat and Jean Philippe Goddard and Cyril Ollivier and Louis Fensterbank},
title = {Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {jul},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201504963},
number = {39},
pages = {11414--11418},
doi = {10.1002/anie.201504963}
}
Cite this
MLA
Copy
Corcé, Vincent, et al. “Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds.” Angewandte Chemie - International Edition, vol. 54, no. 39, Jul. 2015, pp. 11414-11418. https://onlinelibrary.wiley.com/doi/10.1002/anie.201504963.