Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions
Publication type: Journal Article
Publication date: 2015-09-28
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
26412046
General Chemistry
Catalysis
Abstract
The formation and use of iminyl radicals in novel and divergent hydroimination and iminohydroxylation cyclization reactions has been accomplished through the design of a new class of reactive O‐aryl oximes. Owing to their low reduction potentials, the inexpensive organic dye eosin Y could be used as the photocatalyst of the organocatalytic hydroimination reaction. Furthermore, reaction conditions for a unique iminohydroxylation were identified; visible‐light‐mediated electron transfer from novel electron donor–acceptor complexes of the oximes and Et3N was proposed as a key step of this process.
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Metrics
406
Total citations:
406
Citations from 2025:
29
(7.16%)
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GOST
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Davies J. et al. Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 47. pp. 14017-14021.
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Davies J., Booth S. G., Essafi S., Dryfe R. A., Leonori D. Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions // Angewandte Chemie - International Edition. 2015. Vol. 54. No. 47. pp. 14017-14021.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201507641
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201507641
TI - Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions
T2 - Angewandte Chemie - International Edition
AU - Davies, Jacob
AU - Booth, Samuel Guy
AU - Essafi, Stephanie
AU - Dryfe, Robert AW
AU - Leonori, Daniele
PY - 2015
DA - 2015/09/28
PB - Wiley
SP - 14017-14021
IS - 47
VL - 54
PMID - 26412046
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Davies,
author = {Jacob Davies and Samuel Guy Booth and Stephanie Essafi and Robert AW Dryfe and Daniele Leonori},
title = {Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions},
journal = {Angewandte Chemie - International Edition},
year = {2015},
volume = {54},
publisher = {Wiley},
month = {sep},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201507641},
number = {47},
pages = {14017--14021},
doi = {10.1002/anie.201507641}
}
Cite this
MLA
Copy
Davies, Jacob, et al. “Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions.” Angewandte Chemie - International Edition, vol. 54, no. 47, Sep. 2015, pp. 14017-14021. https://onlinelibrary.wiley.com/doi/10.1002/anie.201507641.