Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents
Publication type: Journal Article
Publication date: 2016-04-05
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
27059530
General Chemistry
Catalysis
Abstract
The synthesis of four different bidentate hybrid NHC-thioether ligands is presented. The corresponding palladium nanoparticles are stable in various solvents, depending on the ligand used, and show high chemoselectivity in the hydrogenation of olefins. The solubility of the nanoparticles can be switched multiple times depending on the pH value of the solvent. XPS analysis (which shows a subtle shift in the binding energy) was identified as a convenient tool to establish the binding mode of NHC ligands.
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139
Total citations:
139
Citations from 2025:
8
(5.76%)
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GOST
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Rühling A. et al. Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 19. pp. 5856-5860.
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Rühling A., Schaepe K., Rakers L., Vonhören B., Tegeder P., Ravoo B. J., Glorius F. Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 19. pp. 5856-5860.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201508933
UR - https://doi.org/10.1002/anie.201508933
TI - Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents
T2 - Angewandte Chemie - International Edition
AU - Rühling, A
AU - Schaepe, Kira
AU - Rakers, Lena
AU - Vonhören, Benjamin
AU - Tegeder, Patricia
AU - Ravoo, Bart Jan
AU - Glorius, Frank
PY - 2016
DA - 2016/04/05
PB - Wiley
SP - 5856-5860
IS - 19
VL - 55
PMID - 27059530
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Rühling,
author = {A Rühling and Kira Schaepe and Lena Rakers and Benjamin Vonhören and Patricia Tegeder and Bart Jan Ravoo and Frank Glorius},
title = {Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201508933},
number = {19},
pages = {5856--5860},
doi = {10.1002/anie.201508933}
}
Cite this
MLA
Copy
Rühling, A., et al. “Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents.” Angewandte Chemie - International Edition, vol. 55, no. 19, Apr. 2016, pp. 5856-5860. https://doi.org/10.1002/anie.201508933.