Stable Boron Peroxides with a Subporphyrinato Ligand
Publication type: Journal Article
Publication date: 2016-01-15
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
26773709
General Chemistry
Catalysis
Abstract
Subporphyrin B-peroxides have been synthesized in good yields by acid-catalyzed exchange reactions of subporphyrin B-methoxide with the corresponding hydroperoxides. Thermal dimerization of the subporphyrin B-hydroperoxide provided the peroxo-bridged bis(subporphyrin) quantitatively. These subporphyrin B-peroxides are fairly stable under ambient conditions, which allowed their isolation and full characterization as the first examples of structurally authenticated boron hydroperoxides, acyclic boron organylperoxides, and neutral peroxo-bridged diboron species. The subporphyrin B-peroxides thus prepared were investigated through their crystal structures, IR spectra, and cyclic voltammograms as well as by DFT calculations. The subporphyrin B-hydroperoxide oxidizes triphenylphosphine quantitatively to triphenylphosphine oxide.
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42
Total citations:
42
Citations from 2025:
6
(14.29%)
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GOST
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Tsurumaki E. et al. Stable Boron Peroxides with a Subporphyrinato Ligand // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 7. pp. 2596-2599.
GOST all authors (up to 50)
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Tsurumaki E., Sung J., Kim D. S., Osuka A. Stable Boron Peroxides with a Subporphyrinato Ligand // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 7. pp. 2596-2599.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201511590
UR - https://doi.org/10.1002/anie.201511590
TI - Stable Boron Peroxides with a Subporphyrinato Ligand
T2 - Angewandte Chemie - International Edition
AU - Tsurumaki, Eiji
AU - Sung, Jooyoung
AU - Kim, Dong Sub
AU - Osuka, Atsuhiro
PY - 2016
DA - 2016/01/15
PB - Wiley
SP - 2596-2599
IS - 7
VL - 55
PMID - 26773709
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Tsurumaki,
author = {Eiji Tsurumaki and Jooyoung Sung and Dong Sub Kim and Atsuhiro Osuka},
title = {Stable Boron Peroxides with a Subporphyrinato Ligand},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201511590},
number = {7},
pages = {2596--2599},
doi = {10.1002/anie.201511590}
}
Cite this
MLA
Copy
Tsurumaki, Eiji, et al. “Stable Boron Peroxides with a Subporphyrinato Ligand.” Angewandte Chemie - International Edition, vol. 55, no. 7, Jan. 2016, pp. 2596-2599. https://doi.org/10.1002/anie.201511590.