Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes
Jun Guo
1
,
Zhan Lu
1
Publication type: Journal Article
Publication date: 2016-07-21
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
27440515
General Chemistry
Catalysis
Abstract
A highly chemo-, regio- and stereoselective cobalt-catalyzed Markovnikov hydrosilylation of alkynes was developed. Various functionalized groups, such as halides, free alcohols, free aniline, ketones, esters, amides, and nitriles are tolerated, which may lead to further applications and late-stage derivatizations. To date, this is the most efficient cobalt catalytic system (TOF=65 520 h(-1) ; TOF=turnover frequency) for hydrosilylation of alkynes. The Hiyama-Denmark cross-coupling reactions of vinylsilanes with aryl iodides underwent smoothly to afford 1,1-diarylethenes. A unique regioselectivity-controllable hydrosilylation/hydroboration reaction of alkynes was also described.
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194
Total citations:
194
Citations from 2024:
37
(19.07%)
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GOST
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Guo J., Lu Z. Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 36. pp. 10835-10838.
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Guo J., Lu Z. Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 36. pp. 10835-10838.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201605501
UR - https://doi.org/10.1002/anie.201605501
TI - Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes
T2 - Angewandte Chemie - International Edition
AU - Guo, Jun
AU - Lu, Zhan
PY - 2016
DA - 2016/07/21
PB - Wiley
SP - 10835-10838
IS - 36
VL - 55
PMID - 27440515
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2016_Guo,
author = {Jun Guo and Zhan Lu},
title = {Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/anie.201605501},
number = {36},
pages = {10835--10838},
doi = {10.1002/anie.201605501}
}
Cite this
MLA
Copy
Guo, Jun, and Zhan Lu. “Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes.” Angewandte Chemie - International Edition, vol. 55, no. 36, Jul. 2016, pp. 10835-10838. https://doi.org/10.1002/anie.201605501.