Angewandte Chemie - International Edition

, volume 55 , issue 36 , pages 10839-10843

Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

Ziqing Zuo ¹

Ji Yang ¹

Zheng Huang ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

State Key Laboratory of Organometallic Chemistry; Shanghai Institute of Organic Chemistry; 345 Lingling Road Shanghai 200032 China |

Publication type: Journal Article

Publication date: 2016-08-01

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201605615

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PubMed ID: 27479796

General Chemistry

Catalysis

Abstract

A pyridinebis(oxazoline) cobalt complex is a very efficient precatalyst for the hydrosilylation of terminal alkynes with Ph2 SiH2 , providing α-vinylsilanes with high (Markovnikov) regioselectivity and broad functional-group tolerance. The vinylsilane products can be further converted into geminal borosilanes through Markovnikov hydroboration with pinacolborane and a bis(imino)pyridine cobalt catalyst.

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Lyssenko Konstantin

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DSc in Chemistry, professor

898 publications, 15 180 citations, 2 reviews

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Lomonosov Moscow State University

National Research University Higher School of Economics

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Supramolecular chemistry

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Zuo Z., Yang J., Huang Z. Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 36. pp. 10839-10843.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201605615

UR - https://doi.org/10.1002/anie.201605615

TI - Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

T2 - Angewandte Chemie - International Edition

AU - Zuo, Ziqing

AU - Yang, Ji

AU - Huang, Zheng

PY - 2016

DA - 2016/08/01

PB - Wiley

SP - 10839-10843

IS - 36

VL - 55

PMID - 27479796

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2016_Zuo,

author = {Ziqing Zuo and Ji Yang and Zheng Huang},

title = {Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity},

journal = {Angewandte Chemie - International Edition},

year = {2016},

volume = {55},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/anie.201605615},

number = {36},

pages = {10839--10843},

doi = {10.1002/anie.201605615}

}

MLA

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MLA Copy

Zuo, Ziqing, et al. “Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity.” Angewandte Chemie - International Edition, vol. 55, no. 36, Aug. 2016, pp. 10839-10843. https://doi.org/10.1002/anie.201605615.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)