Angewandte Chemie - International Edition

, volume 55 , issue 41 , pages 12877-12880

Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species

Koichi Nagata ¹

Takahiro Murosaki ²

Tomohiro Agou ^{1, 3}

Shigeru Nagase ¹

Tsukasa Matsuo ²

Norihiro Tokitoh ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

Institute for Chemical Research; Kyoto University; Gokasho, Uji Kyoto 611-0011 Japan |

Department of Applied Chemistry; Faculty of Science and Engineering; Kindai University; 3-4-1 Kowakae, Higashi-Osaka Osaka 577-8502 Japan |

Department of Biomolecular Functional Engineering; College of Engineering; Ibaraki University; 4-12-1 Nakanarisawa, Hitachi Ibaraki 316-8511 Japan |

Publication type: Journal Article

Publication date: 2016-08-16

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201606684

Copy DOI

PubMed ID: 27529165

General Chemistry

Catalysis

Abstract

Activation of dihydrogen by masked dialumenes (Al=Al doubly bonded species) is reported. Reactions of barrelene-type dialumanes, which have the reactivity as masked equivalents of 1,2-diaryldialumenes ArAl=AlAr, with H2 afforded dihydroalumanes ArAlH2 at room temperature (Ar: bulky aryl groups). These dihydroalumanes form hydrogen-bridged dimers [ArHAl(μ-H)]2 in the crystalline state, while a monomer-dimer equilibrium was suggested in solution. The 1,2-diaryldialumenes generated from the barrelene-type dialumanes are the putative active species in the cleavage of H2 .

Found

1 citation

Baranov Evgeniy

PhD in Chemistry

247 publications, 3 263 citations

h-index: 29

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Crystal Chemistry

Organic Chemistry

Organometallic Chemistry

Quantum Chemistry

X-ray diffraction analysis

Top-30

Journals

	1 2 3 4 5 6 7 8
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 8, 18.6% Angewandte Chemie - International Edition 8 publications, 18.6%
Angewandte Chemie	Angewandte Chemie, 7, 16.28% Angewandte Chemie 7 publications, 16.28%
Journal of the American Chemical Society	Journal of the American Chemical Society, 5, 11.63% Journal of the American Chemical Society 5 publications, 11.63%
Chemistry - A European Journal	Chemistry - A European Journal, 4, 9.3% Chemistry - A European Journal 4 publications, 9.3%
Chemical Reviews	Chemical Reviews, 2, 4.65% Chemical Reviews 2 publications, 4.65%
Chemical Communications	Chemical Communications, 2, 4.65% Chemical Communications 2 publications, 4.65%
Chemical Science	Chemical Science, 2, 4.65% Chemical Science 2 publications, 4.65%
Chemistry Letters	Chemistry Letters, 1, 2.33% Chemistry Letters 1 publication, 2.33%
Inorganics	Inorganics, 1, 2.33% Inorganics 1 publication, 2.33%
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry	Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 1, 2.33% Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry 1 publication, 2.33%
Mendeleev Communications	Mendeleev Communications, 1, 2.33% Mendeleev Communications 1 publication, 2.33%
Tetrahedron	Tetrahedron, 1, 2.33% Tetrahedron 1 publication, 2.33%
Organic Letters	Organic Letters, 1, 2.33% Organic Letters 1 publication, 2.33%
ChemPlusChem	ChemPlusChem, 1, 2.33% ChemPlusChem 1 publication, 2.33%
Science and Technology of Advanced Materials	Science and Technology of Advanced Materials, 1, 2.33% Science and Technology of Advanced Materials 1 publication, 2.33%
Journal of Physical Chemistry A	Journal of Physical Chemistry A, 1, 2.33% Journal of Physical Chemistry A 1 publication, 2.33%
Nature Synthesis	Nature Synthesis, 1, 2.33% Nature Synthesis 1 publication, 2.33%
Journal of the Japan Institute of Energy	Journal of the Japan Institute of Energy, 1, 2.33% Journal of the Japan Institute of Energy 1 publication, 2.33%
Inorganic Chemistry	Inorganic Chemistry, 1, 2.33% Inorganic Chemistry 1 publication, 2.33%
	1 2 3 4 5 6 7 8

Publishers

	5 10 15 20
Wiley	Wiley, 20, 46.51% Wiley 20 publications, 46.51%
American Chemical Society (ACS)	American Chemical Society (ACS), 10, 23.26% American Chemical Society (ACS) 10 publications, 23.26%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 9.3% Royal Society of Chemistry (RSC) 4 publications, 9.3%
Oxford University Press	Oxford University Press, 1, 2.33% Oxford University Press 1 publication, 2.33%
MDPI	MDPI, 1, 2.33% MDPI 1 publication, 2.33%
The Society of Synthetic Organic Chemistry, Japan	The Society of Synthetic Organic Chemistry, Japan, 1, 2.33% The Society of Synthetic Organic Chemistry, Japan 1 publication, 2.33%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 2.33% OOO Zhurnal "Mendeleevskie Soobshcheniya" 1 publication, 2.33%
Elsevier	Elsevier, 1, 2.33% Elsevier 1 publication, 2.33%
Taylor & Francis	Taylor & Francis, 1, 2.33% Taylor & Francis 1 publication, 2.33%
Research Square Platform LLC	Research Square Platform LLC, 1, 2.33% Research Square Platform LLC 1 publication, 2.33%
Springer Nature	Springer Nature, 1, 2.33% Springer Nature 1 publication, 2.33%
The Japan Institute of Energy	The Japan Institute of Energy, 1, 2.33% The Japan Institute of Energy 1 publication, 2.33%
	5 10 15 20

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Nagata K. et al. Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 41. pp. 12877-12880.

GOST all authors (up to 50) Copy

Nagata K., Murosaki T., Agou T., Nagase S., Matsuo T., Tokitoh N. Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 41. pp. 12877-12880.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/anie.201606684

UR - https://doi.org/10.1002/anie.201606684

TI - Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species

T2 - Angewandte Chemie - International Edition

AU - Nagata, Koichi

AU - Murosaki, Takahiro

AU - Agou, Tomohiro

AU - Nagase, Shigeru

AU - Matsuo, Tsukasa

AU - Tokitoh, Norihiro

PY - 2016

DA - 2016/08/16

PB - Wiley

SP - 12877-12880

IS - 41

VL - 55

PMID - 27529165

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2016_Nagata,

author = {Koichi Nagata and Takahiro Murosaki and Tomohiro Agou and Shigeru Nagase and Tsukasa Matsuo and Norihiro Tokitoh},

title = {Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species},

journal = {Angewandte Chemie - International Edition},

year = {2016},

volume = {55},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/anie.201606684},

number = {41},

pages = {12877--12880},

doi = {10.1002/anie.201606684}

}

MLA

Cite this

MLA Copy

Nagata, Koichi, et al. “Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species.” Angewandte Chemie - International Edition, vol. 55, no. 41, Aug. 2016, pp. 12877-12880. https://doi.org/10.1002/anie.201606684.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)