Angewandte Chemie - International Edition, volume 56, issue 7, pages 1890-1893
Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst
Publication type: Journal Article
Publication date: 2017-01-12
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Herein we describe the first homogeneous non-noble metal catalyst for the hydrogenation of CO2 to methanol. The catalyst is formed in situ from [Co(acac)3 ], Triphos, and HNTf2 and enables the reaction to be performed at 100 °C without a decrease in activity. Kinetic studies suggest an inner-sphere mechanism, and in situ NMR and MS experiments reveal the formation of the active catalyst through slow removal of the acetylacetonate ligands.
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Schneidewind J. et al. Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 7. pp. 1890-1893.
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Schneidewind J., Adam R., Baumann W., Jackstell R., Beller M. Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 7. pp. 1890-1893.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201609077
UR - https://doi.org/10.1002/anie.201609077
TI - Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst
T2 - Angewandte Chemie - International Edition
AU - Baumann, Wolfgang
AU - Schneidewind, Jacob
AU - Beller, Matthias
AU - Adam, Rosa
AU - Jackstell, Ralf
PY - 2017
DA - 2017/01/12
PB - Wiley
SP - 1890-1893
IS - 7
VL - 56
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex
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@article{2017_Schneidewind,
author = {Wolfgang Baumann and Jacob Schneidewind and Matthias Beller and Rosa Adam and Ralf Jackstell},
title = {Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201609077},
number = {7},
pages = {1890--1893},
doi = {10.1002/anie.201609077}
}
Cite this
MLA
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Schneidewind, Jacob, et al. “Low-Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst.” Angewandte Chemie - International Edition, vol. 56, no. 7, Jan. 2017, pp. 1890-1893. https://doi.org/10.1002/anie.201609077.