Angewandte Chemie - International Edition, volume 56, issue 9, pages 2318-2323
CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface
Kim Larmier
1
,
Wei Chih Liao
1
,
Ryuji Kikuchi
1
,
Erwin Lam
1
,
René Verel
1
,
Atul Bansode
2
,
Atsushi Urakawa
2
,
Aleix Comas Vives
1
,
Publication type: Journal Article
Publication date: 2017-01-23
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Methanol synthesis by CO2 hydrogenation is a key process in a methanol-based economy. This reaction is catalyzed by supported copper nanoparticles and displays strong support or promoter effects. Zirconia is known to enhance both the methanol production rate and the selectivity. Nevertheless, the origin of this observation and the reaction mechanisms associated with the conversion of CO2 to methanol still remain unknown. A mechanistic study of the hydrogenation of CO2 on Cu/ZrO2 is presented. Using kinetics, in situ IR and NMR spectroscopies, and isotopic labeling strategies, surface intermediates evolved during CO2 hydrogenation were observed at different pressures. Combined with DFT calculations, it is shown that a formate species is the reaction intermediate and that the zirconia/copper interface is crucial for the conversion of this intermediate to methanol.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Larmier K. et al. CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 9. pp. 2318-2323.
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Larmier K., Liao W. C., Kikuchi R., Lam E., Verel R., Bansode A., Urakawa A., Comas Vives A., Copéret C. CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 9. pp. 2318-2323.
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TY - JOUR
DO - 10.1002/anie.201610166
UR - https://doi.org/10.1002/anie.201610166
TI - CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface
T2 - Angewandte Chemie - International Edition
AU - Larmier, Kim
AU - Lam, Erwin
AU - Comas Vives, Aleix
AU - Copéret, Christophe
AU - Liao, Wei Chih
AU - Kikuchi, Ryuji
AU - Verel, René
AU - Bansode, Atul
AU - Urakawa, Atsushi
PY - 2017
DA - 2017/01/23 00:00:00
PB - Wiley
SP - 2318-2323
IS - 9
VL - 56
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2017_Larmier,
author = {Kim Larmier and Erwin Lam and Aleix Comas Vives and Christophe Copéret and Wei Chih Liao and Ryuji Kikuchi and René Verel and Atul Bansode and Atsushi Urakawa},
title = {CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201610166},
number = {9},
pages = {2318--2323},
doi = {10.1002/anie.201610166}
}
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MLA
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Larmier, Kim, et al. “CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface.” Angewandte Chemie - International Edition, vol. 56, no. 9, Jan. 2017, pp. 2318-2323. https://doi.org/10.1002/anie.201610166.