(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
1
Core R&D The Dow Chemical Company 2200 West Salzburg Road Auburn MI 48611 USA
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Publication type: Journal Article
Publication date: 2017-02-17
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
28211252
General Chemistry
Catalysis
Abstract
Cobalt-catalyzed anti-Markovnikov reactions that involve siloxy- or alkoxy(vinyl)silanes and siloxy- or alkoxyhydrosilanes are disclosed. More than 25 new cobalt-(aminomethyl)pyridine complexes were developed as catalysts for the hydrosilylation of industry-relevant and challenging siloxy- or alkoxy-terminated vinylsilanes. These transformations typically proceed in the presence of 0.25 mol % of the cobalt complex with 0.75 mol % of the alkylating agent to afford the desired products in up to >98 % yield with >98 % anti-Markovnikov selectivity in 30 min. The current protocol shows a broad substrate scope, delivering more than 25 siloxanes with siloxy or alkoxy functional groups at both termini, and can also be applied to polymeric vinyl- and hydrosiloxanes.
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Total citations:
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Citations from 2024:
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(30.62%)
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Lee K. (Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 13. pp. 3665-3669.
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Lee K. (Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 13. pp. 3665-3669.
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TY - JOUR
DO - 10.1002/anie.201612460
UR - https://doi.org/10.1002/anie.201612460
TI - (Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
T2 - Angewandte Chemie - International Edition
AU - Lee, Kang-Sang
PY - 2017
DA - 2017/02/17
PB - Wiley
SP - 3665-3669
IS - 13
VL - 56
PMID - 28211252
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Lee,
author = {Kang-Sang Lee},
title = {(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201612460},
number = {13},
pages = {3665--3669},
doi = {10.1002/anie.201612460}
}
Cite this
MLA
Copy
Lee, Kang-Sang. “(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes.” Angewandte Chemie - International Edition, vol. 56, no. 13, Feb. 2017, pp. 3665-3669. https://doi.org/10.1002/anie.201612460.