volume 56 issue 15 pages 4328-4332

Cobalt-Catalyzed Z -Selective Hydrosilylation of Terminal Alkynes

Publication typeJournal Article
Publication date2017-03-07
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
A cobalt-catalyzed Z-selective hydrosilylation of alkynes has been developed relying on catalysts generated from bench-stable Co(OAc)2 and pyridine-2,6-diimine (PDI) ligands. A variety of functionalized aromatic and aliphatic alkynes undergo this transformation, yielding Z-vinylsilanes in high yields with excellent selectivities (Z/E ratio ranges from 90:10 to >99:1). The addition of a catalytic amount of phenol effectively suppressed the Z/E-isomerization of the Z-vinylsilanes that formed under catalytic conditions.
Found 
Found 

Top-30

Journals

2
4
6
8
10
12
14
16
18
Organic Letters
17 publications, 11.18%
Angewandte Chemie
12 publications, 7.89%
Angewandte Chemie - International Edition
12 publications, 7.89%
ACS Catalysis
8 publications, 5.26%
Organometallics
8 publications, 5.26%
Journal of the American Chemical Society
6 publications, 3.95%
Organic Chemistry Frontiers
6 publications, 3.95%
Chemical Communications
5 publications, 3.29%
European Journal of Inorganic Chemistry
4 publications, 2.63%
Applied Organometallic Chemistry
4 publications, 2.63%
ChemCatChem
4 publications, 2.63%
Catalysis Science and Technology
4 publications, 2.63%
RSC Advances
3 publications, 1.97%
Journal of Catalysis
3 publications, 1.97%
Chemistry - A European Journal
3 publications, 1.97%
Journal of Organic Chemistry
3 publications, 1.97%
Nature Communications
2 publications, 1.32%
Coordination Chemistry Reviews
2 publications, 1.32%
Chemistry - An Asian Journal
2 publications, 1.32%
Chinese Journal of Chemistry
2 publications, 1.32%
Chemical Record
2 publications, 1.32%
Chemical Reviews
2 publications, 1.32%
Chemical Science
2 publications, 1.32%
New Journal of Chemistry
2 publications, 1.32%
Synthesis
2 publications, 1.32%
Dalton Transactions
2 publications, 1.32%
Polymers
1 publication, 0.66%
iScience
1 publication, 0.66%
Journal of Organometallic Chemistry
1 publication, 0.66%
2
4
6
8
10
12
14
16
18

Publishers

10
20
30
40
50
Wiley
50 publications, 32.89%
American Chemical Society (ACS)
45 publications, 29.61%
Royal Society of Chemistry (RSC)
28 publications, 18.42%
Elsevier
16 publications, 10.53%
Springer Nature
4 publications, 2.63%
MDPI
2 publications, 1.32%
Georg Thieme Verlag KG
2 publications, 1.32%
EDP Sciences
2 publications, 1.32%
Walter de Gruyter
1 publication, 0.66%
American Association for the Advancement of Science (AAAS)
1 publication, 0.66%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.66%
10
20
30
40
50
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
152
Share
Cite this
GOST |
Cite this
GOST Copy
Teo W. J. et al. Cobalt-Catalyzed Z -Selective Hydrosilylation of Terminal Alkynes // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 15. pp. 4328-4332.
GOST all authors (up to 50) Copy
Teo W. J., Wang C., Tan Y. W., Ge S. Cobalt-Catalyzed Z -Selective Hydrosilylation of Terminal Alkynes // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 15. pp. 4328-4332.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.201700868
UR - https://doi.org/10.1002/anie.201700868
TI - Cobalt-Catalyzed Z -Selective Hydrosilylation of Terminal Alkynes
T2 - Angewandte Chemie - International Edition
AU - Teo, Wei Jie
AU - Wang, Chao
AU - Tan, Ye Wei
AU - Ge, Shaozhong
PY - 2017
DA - 2017/03/07
PB - Wiley
SP - 4328-4332
IS - 15
VL - 56
PMID - 28267265
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Teo,
author = {Wei Jie Teo and Chao Wang and Ye Wei Tan and Shaozhong Ge},
title = {Cobalt-Catalyzed Z -Selective Hydrosilylation of Terminal Alkynes},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201700868},
number = {15},
pages = {4328--4332},
doi = {10.1002/anie.201700868}
}
MLA
Cite this
MLA Copy
Teo, Wei Jie, et al. “Cobalt-Catalyzed Z -Selective Hydrosilylation of Terminal Alkynes.” Angewandte Chemie - International Edition, vol. 56, no. 15, Mar. 2017, pp. 4328-4332. https://doi.org/10.1002/anie.201700868.