Angewandte Chemie - International Edition, volume 56, issue 32, pages 9415-9419
Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation
Publication type: Journal Article
Publication date: 2017-07-13
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
C-H/C-C functionalizations with methylenecyclopropanes (MCPs) were accomplished with a versatile base-metal catalyst. A robust manganese(I) complex enabled the expedient annulation of MCPs by synthetically meaningful ketimines to deliver, upon one-pot hydroarylation, densely substituted polycylic anilines in a step-economical fashion. Mechanistic studies provided strong support for a facile organometallic C-H manganation, while typical cobalt, ruthenium, rhodium, and palladium catalysts were found completely ineffective.
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Citations by publishers
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Wiley
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Thieme
1 publication, 0.74%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.74%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Liang Yu. F. et al. Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 32. pp. 9415-9419.
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Liang Yu. F., Müller V. L., Liu W., Münch A., Stalke D., Ackermann L. Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 32. pp. 9415-9419.
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TY - JOUR
DO - 10.1002/anie.201704767
UR - https://doi.org/10.1002/anie.201704767
TI - Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation
T2 - Angewandte Chemie - International Edition
AU - Ackermann, Lutz
AU - Liang, Yu Feng
AU - Müller, Valentin L.
AU - Liu, Weiping
AU - Münch, Annika
AU - Stalke, Dietmar
PY - 2017
DA - 2017/07/13 00:00:00
PB - Wiley
SP - 9415-9419
IS - 32
VL - 56
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2017_Liang,
author = {Lutz Ackermann and Yu Feng Liang and Valentin L. Müller and Weiping Liu and Annika Münch and Dietmar Stalke},
title = {Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/anie.201704767},
number = {32},
pages = {9415--9419},
doi = {10.1002/anie.201704767}
}
Cite this
MLA
Copy
Liang, Yu. Feng, et al. “Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation.” Angewandte Chemie - International Edition, vol. 56, no. 32, Jul. 2017, pp. 9415-9419. https://doi.org/10.1002/anie.201704767.