Angewandte Chemie - International Edition

, volume 56 , issue 32 , pages 9415-9419

Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation

Yu Feng Liang ¹

Valentin L. Müller ¹

Weiping Liu ¹

Annika Münch ²

Dietmar Stalke ²

Lutz Ackermann ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Institut für Organische und Biomolekulare Chemie; Georg-August-Universität Göttingen; Tammannstraße 2 37077 Göttingen Germany |

Institut für Anorganische Chemie; Georg-August-Universität Göttingen; Tammannstraße 4 37077 Göttingen Germany |

Publication type: Journal Article

Publication date: 2017-07-13

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201704767

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PubMed ID: 28605110

General Chemistry

Catalysis

Abstract

C-H/C-C functionalizations with methylenecyclopropanes (MCPs) were accomplished with a versatile base-metal catalyst. A robust manganese(I) complex enabled the expedient annulation of MCPs by synthetically meaningful ketimines to deliver, upon one-pot hydroarylation, densely substituted polycylic anilines in a step-economical fashion. Mechanistic studies provided strong support for a facile organometallic C-H manganation, while typical cobalt, ruthenium, rhodium, and palladium catalysts were found completely ineffective.

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145

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GOST |

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GOST Copy

Liang Yu. F. et al. Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 32. pp. 9415-9419.

GOST all authors (up to 50) Copy

Liang Yu. F., Müller V. L., Liu W., Münch A., Stalke D., Ackermann L. Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 32. pp. 9415-9419.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201704767

UR - https://doi.org/10.1002/anie.201704767

TI - Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation

T2 - Angewandte Chemie - International Edition

AU - Liang, Yu Feng

AU - Müller, Valentin L.

AU - Liu, Weiping

AU - Münch, Annika

AU - Stalke, Dietmar

AU - Ackermann, Lutz

PY - 2017

DA - 2017/07/13

PB - Wiley

SP - 9415-9419

IS - 32

VL - 56

PMID - 28605110

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2017_Liang,

author = {Yu Feng Liang and Valentin L. Müller and Weiping Liu and Annika Münch and Dietmar Stalke and Lutz Ackermann},

title = {Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation},

journal = {Angewandte Chemie - International Edition},

year = {2017},

volume = {56},

publisher = {Wiley},

month = {jul},

url = {https://doi.org/10.1002/anie.201704767},

number = {32},

pages = {9415--9419},

doi = {10.1002/anie.201704767}

}

MLA

Cite this

MLA Copy

Liang, Yu. Feng, et al. “Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation.” Angewandte Chemie - International Edition, vol. 56, no. 32, Jul. 2017, pp. 9415-9419. https://doi.org/10.1002/anie.201704767.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)