Angewandte Chemie - International Edition, volume 57, issue 10, pages 2592-2595
Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages
Wenquan Zhang
1
,
Kangcai Wang
1
,
Juecheng Li
1
,
Zhi-En Lin
1, 2
,
Siwei Song
1
,
Shiliang Huang
1
,
Yu Liu
1
,
Nie Fude
1
,
Qinghua Zhang
1
1
Research Center of Energetic Material Genome Science; Institute of Chemical Materials; China Academy of Engineering Physics (CAEP); Mianyang 621900 China
|
Publication type: Journal Article
Publication date: 2018-02-02
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The experimental detection and synthesis of pentazole (HN5 ) and its anion (cyclo-N5- ) have been actively pursued for the past hundred years. The synthesis of an aesthetic three-dimensional metal-pentazolate framework (denoted as MPF-1) is presented. It consists of sodium ions and cyclo-N5- anions in which the isolated cyclo-N5- anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20 N60 and Na24 N60 ) through strong metal coordination bonds. The compound MPF-1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo-N5- salts. This finding offers a new approach to create metal-pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials.
Top-30
Journals
|
1
2
3
4
5
6
7
8
9
|
|
|
CrystEngComm
9 publications, 8.65%
|
|
|
Crystal Growth and Design
5 publications, 4.81%
|
|
|
Science China Materials
4 publications, 3.85%
|
|
|
Journal of Physical Chemistry C
4 publications, 3.85%
|
|
|
Journal of Physical Chemistry Letters
4 publications, 3.85%
|
|
|
Inorganic Chemistry
4 publications, 3.85%
|
|
|
Journal of the American Chemical Society
3 publications, 2.88%
|
|
|
Chemical Engineering Journal
3 publications, 2.88%
|
|
|
Energetic Materials Frontiers
3 publications, 2.88%
|
|
|
Chemistry - An Asian Journal
3 publications, 2.88%
|
|
|
Dalton Transactions
3 publications, 2.88%
|
|
|
Physical Chemistry Chemical Physics
3 publications, 2.88%
|
|
|
Scientific Reports
2 publications, 1.92%
|
|
|
Journal of Molecular Structure
2 publications, 1.92%
|
|
|
Engineering
2 publications, 1.92%
|
|
|
FirePhysChem
2 publications, 1.92%
|
|
|
Polyhedron
2 publications, 1.92%
|
|
|
Angewandte Chemie - International Edition
2 publications, 1.92%
|
|
|
Angewandte Chemie
2 publications, 1.92%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
2 publications, 1.92%
|
|
|
Chemistry of Materials
2 publications, 1.92%
|
|
|
Journal of Materials Chemistry A
2 publications, 1.92%
|
|
|
Chemical Communications
2 publications, 1.92%
|
|
|
New Journal of Chemistry
2 publications, 1.92%
|
|
|
Chemical Reviews
1 publication, 0.96%
|
|
|
Nature Chemistry
1 publication, 0.96%
|
|
|
AIP Advances
1 publication, 0.96%
|
|
|
Royal Society Open Science
1 publication, 0.96%
|
|
|
Nature Communications
1 publication, 0.96%
|
|
|
1
2
3
4
5
6
7
8
9
|
Publishers
|
5
10
15
20
25
30
|
|
|
American Chemical Society (ACS)
29 publications, 27.88%
|
|
|
Royal Society of Chemistry (RSC)
25 publications, 24.04%
|
|
|
Elsevier
20 publications, 19.23%
|
|
|
Wiley
14 publications, 13.46%
|
|
|
Springer Nature
11 publications, 10.58%
|
|
|
IOP Publishing
2 publications, 1.92%
|
|
|
AIP Publishing
1 publication, 0.96%
|
|
|
The Royal Society
1 publication, 0.96%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.96%
|
|
|
5
10
15
20
25
30
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Zhang W. et al. Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 10. pp. 2592-2595.
GOST all authors (up to 50)
Copy
Zhang W., Wang K., Li J., Lin Z., Song S., Huang S., Liu Yu., Fude N., Zhang Q. Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 10. pp. 2592-2595.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201710602
UR - https://doi.org/10.1002/anie.201710602
TI - Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages
T2 - Angewandte Chemie - International Edition
AU - Wang, Kangcai
AU - Li, Juecheng
AU - Huang, Shiliang
AU - Zhang, Qinghua
AU - Zhang, Wenquan
AU - Lin, Zhi-En
AU - Song, Siwei
AU - Liu, Yu
AU - Fude, Nie
PY - 2018
DA - 2018/02/02
PB - Wiley
SP - 2592-2595
IS - 10
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex
Copy
@article{2018_Zhang,
author = {Kangcai Wang and Juecheng Li and Shiliang Huang and Qinghua Zhang and Wenquan Zhang and Zhi-En Lin and Siwei Song and Yu Liu and Nie Fude},
title = {Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201710602},
number = {10},
pages = {2592--2595},
doi = {10.1002/anie.201710602}
}
Cite this
MLA
Copy
Zhang, Wenquan, et al. “Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages.” Angewandte Chemie - International Edition, vol. 57, no. 10, Feb. 2018, pp. 2592-2595. https://doi.org/10.1002/anie.201710602.