Angewandte Chemie - International Edition, volume 57, issue 10, pages 2592-2595
Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages
Wenquan Zhang
1
,
Kangcai Wang
1
,
Juecheng Li
1
,
Zhi-En Lin
1, 2
,
Siwei Song
1
,
Shiliang Huang
1
,
Yu Liu
1
,
Nie Fude
1
,
Qinghua Zhang
1
1
Research Center of Energetic Material Genome Science; Institute of Chemical Materials; China Academy of Engineering Physics (CAEP); Mianyang 621900 China
|
Publication type: Journal Article
Publication date: 2018-02-02
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The experimental detection and synthesis of pentazole (HN5 ) and its anion (cyclo-N5- ) have been actively pursued for the past hundred years. The synthesis of an aesthetic three-dimensional metal-pentazolate framework (denoted as MPF-1) is presented. It consists of sodium ions and cyclo-N5- anions in which the isolated cyclo-N5- anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20 N60 and Na24 N60 ) through strong metal coordination bonds. The compound MPF-1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo-N5- salts. This finding offers a new approach to create metal-pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials.
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Zhang W. et al. Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 10. pp. 2592-2595.
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Zhang W., Wang K., Li J., Lin Z., Song S., Huang S., Liu Yu., Fude N., Zhang Q. Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 10. pp. 2592-2595.
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TY - JOUR
DO - 10.1002/anie.201710602
UR - https://doi.org/10.1002/anie.201710602
TI - Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages
T2 - Angewandte Chemie - International Edition
AU - Wang, Kangcai
AU - Li, Juecheng
AU - Huang, Shiliang
AU - Zhang, Qinghua
AU - Zhang, Wenquan
AU - Lin, Zhi-En
AU - Song, Siwei
AU - Liu, Yu
AU - Fude, Nie
PY - 2018
DA - 2018/02/02 00:00:00
PB - Wiley
SP - 2592-2595
IS - 10
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2018_Zhang,
author = {Kangcai Wang and Juecheng Li and Shiliang Huang and Qinghua Zhang and Wenquan Zhang and Zhi-En Lin and Siwei Song and Yu Liu and Nie Fude},
title = {Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.201710602},
number = {10},
pages = {2592--2595},
doi = {10.1002/anie.201710602}
}
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Zhang, Wenquan, et al. “Stabilization of the Pentazolate Anion in a Zeolitic Architecture with Na20 N60 and Na24 N60 Nanocages.” Angewandte Chemie - International Edition, vol. 57, no. 10, Feb. 2018, pp. 2592-2595. https://doi.org/10.1002/anie.201710602.