Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid
Publication type: Journal Article
Publication date: 2018-01-12
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
29240282
General Chemistry
Catalysis
Abstract
No neutral silicon Lewis super acids are known to date. We report on the synthesis of bis(perchlorocatecholato)silane and verify its Lewis super acidity by computation (DLPNO-CCSD(T)) and experiment (fluoride abstraction from SbF6- ). The exceptional affinity towards donors is further demonstrated by, for example, the characterization of an unprecedented SiO4 F2 dianion and applied in the first hydrodefluorination reaction catalyzed by a neutral silicon Lewis acid. Given the strength and convenient access to this new Lewis acid, versatile applications might be foreseen.
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Metrics
124
Total citations:
124
Citations from 2025:
12
(9.68%)
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MLA
Cite this
GOST
Copy
Maskey R. et al. Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 6. pp. 1717-1720.
GOST all authors (up to 50)
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Maskey R., Schädler M., Legler C., Greb L. Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 6. pp. 1717-1720.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201712155
UR - https://doi.org/10.1002/anie.201712155
TI - Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid
T2 - Angewandte Chemie - International Edition
AU - Maskey, Rezisha
AU - Schädler, Marcel
AU - Legler, Claudia
AU - Greb, L
PY - 2018
DA - 2018/01/12
PB - Wiley
SP - 1717-1720
IS - 6
VL - 57
PMID - 29240282
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Maskey,
author = {Rezisha Maskey and Marcel Schädler and Claudia Legler and L Greb},
title = {Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.201712155},
number = {6},
pages = {1717--1720},
doi = {10.1002/anie.201712155}
}
Cite this
MLA
Copy
Maskey, Rezisha, et al. “Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid.” Angewandte Chemie - International Edition, vol. 57, no. 6, Jan. 2018, pp. 1717-1720. https://doi.org/10.1002/anie.201712155.