Angewandte Chemie - International Edition, volume 57, issue 21, pages 6337-6341
Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr‐Salen Catalyst To Access ABA Block Polyesters
Publication type: Journal Article
Publication date: 2018-04-27
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
PubMed ID:
29518288
General Chemistry
Catalysis
Abstract
ABA triblock polyesters are synthesized using a commercially available chromium salen catalyst, in one pot, from monomer mixtures comprising epoxide, anhydride and lactone. The catalysis is highly selective and applies a single catalyst in two distinct pathways. It occurs first by epoxide/anhydride ring-opening copolymerization and subsequently by lactone ring-opening polymerization. It is used to produce various new ABA polyester polyols; these polyols can undergo post-functionalization and chain-extension reactions. The ability to use a commercial catalyst and switchable catalysis with monomer mixtures is expected to facilitate future explorations of new classes of block polymers.
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Stößer T., Williams C. Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr‐Salen Catalyst To Access ABA Block Polyesters // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 21. pp. 6337-6341.
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Stößer T., Williams C. Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr‐Salen Catalyst To Access ABA Block Polyesters // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 21. pp. 6337-6341.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201801400
UR - https://doi.org/10.1002/anie.201801400
TI - Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr‐Salen Catalyst To Access ABA Block Polyesters
T2 - Angewandte Chemie - International Edition
AU - Stößer, Tim
AU - Williams, Charlotte
PY - 2018
DA - 2018/04/27
PB - Wiley
SP - 6337-6341
IS - 21
VL - 57
PMID - 29518288
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2018_Stößer,
author = {Tim Stößer and Charlotte Williams},
title = {Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr‐Salen Catalyst To Access ABA Block Polyesters},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201801400},
number = {21},
pages = {6337--6341},
doi = {10.1002/anie.201801400}
}
Cite this
MLA
Copy
Stößer, Tim, and Charlotte Williams. “Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr‐Salen Catalyst To Access ABA Block Polyesters.” Angewandte Chemie - International Edition, vol. 57, no. 21, Apr. 2018, pp. 6337-6341. https://doi.org/10.1002/anie.201801400.