Angewandte Chemie - International Edition, volume 57, issue 22, pages 6512-6516
Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes.
Publication type: Journal Article
Publication date: 2018-05-28
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
A cobalt-catalyzed chelation-assisted tandem C-H activation/C-C cleavage/C-H cyclization of aromatic amides with alkylidenecyclopropanes is reported. This process allows the sequential formation of two C-C bonds, which is in sharp contrast to previous reports on using rhodium catalysts for the formation of C-N bonds. Here the inexpensive catalyst system exhibits good functional-group compatibility and relatively broad substrate scope. The desired products can be easily transformed into polycyclic lactones with m-CPBA. Mechanistic studies revealed that the tandem reaction proceeds through a C-H cobaltation, β-carbon elimination, and intramolecular C-H cobaltation sequence.
Top-30
Citations by journals
|
2
4
6
8
10
12
14
16
|
|
|
Organic Letters
16 publications, 18.39%
|
|
|
ACS Catalysis
7 publications, 8.05%
|
|
|
Advanced Synthesis and Catalysis
6 publications, 6.9%
|
|
|
Chemical Communications
6 publications, 6.9%
|
|
|
Angewandte Chemie
5 publications, 5.75%
|
|
|
Angewandte Chemie - International Edition
5 publications, 5.75%
|
|
|
Journal of Organic Chemistry
4 publications, 4.6%
|
|
|
Journal of the American Chemical Society
4 publications, 4.6%
|
|
|
Organic Chemistry Frontiers
3 publications, 3.45%
|
|
|
Chemical Science
2 publications, 2.3%
|
|
|
Communications Chemistry
2 publications, 2.3%
|
|
|
Chemistry - An Asian Journal
2 publications, 2.3%
|
|
|
Chemical Record
2 publications, 2.3%
|
|
|
European Journal of Organic Chemistry
2 publications, 2.3%
|
|
|
Organometallics
2 publications, 2.3%
|
|
|
Organic and Biomolecular Chemistry
2 publications, 2.3%
|
|
|
Molecules
1 publication, 1.15%
|
|
|
Nature Communications
1 publication, 1.15%
|
|
|
Asian Journal of Organic Chemistry
1 publication, 1.15%
|
|
|
ChemSusChem
1 publication, 1.15%
|
|
|
Chemistry - A European Journal
1 publication, 1.15%
|
|
|
Chemical Reviews
1 publication, 1.15%
|
|
|
RSC Advances
1 publication, 1.15%
|
|
|
Organic Reaction Mechanisms
1 publication, 1.15%
|
|
|
Journal of Catalysis
1 publication, 1.15%
|
|
|
Chem Catalysis
1 publication, 1.15%
|
|
|
Chinese Chemical Letters
1 publication, 1.15%
|
|
|
Advanced Science
1 publication, 1.15%
|
|
|
Russian Chemical Reviews
1 publication, 1.15%
|
|
|
2
4
6
8
10
12
14
16
|
Citations by publishers
|
5
10
15
20
25
30
35
|
|
|
American Chemical Society (ACS)
34 publications, 39.08%
|
|
|
Wiley
29 publications, 33.33%
|
|
|
Royal Society of Chemistry (RSC)
14 publications, 16.09%
|
|
|
Springer Nature
3 publications, 3.45%
|
|
|
Elsevier
3 publications, 3.45%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 1.15%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.15%
|
|
|
5
10
15
20
25
30
35
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0],"imageUrls":["","","","","","",""],"datasets":[{"label":"Citations number","data":[6,20,15,21,13,7,5],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["6.9","22.99","17.24","24.14","14.94","8.05","5.75"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Organic Letters","ACS Catalysis","Advanced Synthesis and Catalysis","Chemical Communications","Angewandte Chemie","Angewandte Chemie - International Edition","Journal of Organic Chemistry","Journal of the American Chemical Society","Organic Chemistry Frontiers","Chemical Science","Communications Chemistry","Chemistry - An Asian Journal","Chemical Record","European Journal of Organic Chemistry","Organometallics","Organic and Biomolecular Chemistry","Molecules","Nature Communications","Asian Journal of Organic Chemistry","ChemSusChem","Chemistry - A European Journal","Chemical Reviews","RSC Advances","Organic Reaction Mechanisms","Journal of Catalysis","Chem Catalysis","Chinese Chemical Letters","Advanced Science","Russian Chemical Reviews"],"ids":[3315,4873,3906,9073,25450,19215,8697,4813,3991,9646,1368,10120,22413,19472,1409,541,1770,3231,9409,6896,24708,13718,3100,42256,20883,26939,20341,4130,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[16,7,6,6,5,5,4,4,3,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[18.39,8.05,6.9,6.9,5.75,5.75,4.6,4.6,3.45,2.3,2.3,2.3,2.3,2.3,2.3,2.3,1.15,1.15,1.15,1.15,1.15,1.15,1.15,1.15,1.15,1.15,1.15,1.15,1.15],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Springer Nature","Elsevier","Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,123,8,17,202,9422],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[34,29,14,3,3,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[39.08,33.33,16.09,3.45,3.45,1.15,1.15],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,1,1,1,0,0],"percentage":["0","1.15","1.15","1.15","1.15","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[6,19,14,18,9,7,5],"percentage":["6.9","21.84","16.09","20.69","10.34","8.05","5.75"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,2,3,0,0],"percentage":["0","0","0","2.3","3.45","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,4,7,7,1,0,0],"percentage":["1.15","4.6","8.05","8.05","1.15","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[5,14,8,11,8,5,5],"percentage":["5.75","16.09","9.2","12.64","9.2","5.75","5.75"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,0,3,4,2,0],"percentage":["0","2.3","0","3.45","4.6","2.3","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Li M., Kwong F. Y. Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes. // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 22. pp. 6512-6516.
GOST all authors (up to 50)
Copy
Li M., Kwong F. Y. Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes. // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 22. pp. 6512-6516.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201801706
UR - https://doi.org/10.1002/anie.201801706
TI - Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes.
T2 - Angewandte Chemie - International Edition
AU - Li, Mingliang
AU - Kwong, Fuk Yee
PY - 2018
DA - 2018/05/28 00:00:00
PB - Wiley
SP - 6512-6516
IS - 22
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex
Copy
@article{2018_Li,
author = {Mingliang Li and Fuk Yee Kwong},
title = {Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes.},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/anie.201801706},
number = {22},
pages = {6512--6516},
doi = {10.1002/anie.201801706}
}
Cite this
MLA
Copy
Li, Mingliang, and Fuk Yee Kwong. “Cobalt-Catalyzed Tandem C-H Activation/C-C Cleavage/C-H Cyclization of Aromatic Amides with Alkylidenecyclopropanes..” Angewandte Chemie - International Edition, vol. 57, no. 22, May. 2018, pp. 6512-6516. https://doi.org/10.1002/anie.201801706.