Visible‐Light‐Mediated Metal‐Free Synthesis of Trifluoromethylselenolated Arenes
Тип публикации: Journal Article
Дата публикации: 2018-08-01
scimago Q1
wos Q1
БС1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
29985549
General Chemistry
Catalysis
Краткое описание
The first visible‐light‐mediated synthesis of trifluoromethylselenolated arenes under metal‐free conditions is reported. The use of an organic photocatalyst enables the trifluoromethylselenolation of arene diazonium salts using the shelf‐stable reagent trifluoromethyl tolueneselenosulfonate at room temperature. The reaction does not require the presence of any additives and shows high functional‐group tolerance, covering a very broad range of starting materials. Mechanistic investigations, including EPR spectroscopy, luminescence investigations, and cyclic voltammetry allow rationalization of the reaction mechanism.
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ГОСТ
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Ghiazza C. et al. Visible‐Light‐Mediated Metal‐Free Synthesis of Trifluoromethylselenolated Arenes // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 36. pp. 11781-11785.
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Ghiazza C., Debrauwer V., Monnereau C., Khrouz L., Médebielle M., Billard T., Tlili A. Visible‐Light‐Mediated Metal‐Free Synthesis of Trifluoromethylselenolated Arenes // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 36. pp. 11781-11785.
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TY - JOUR
DO - 10.1002/anie.201806165
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201806165
TI - Visible‐Light‐Mediated Metal‐Free Synthesis of Trifluoromethylselenolated Arenes
T2 - Angewandte Chemie - International Edition
AU - Ghiazza, Clément
AU - Debrauwer, Vincent
AU - Monnereau, Cyrille
AU - Khrouz, Lhoussain
AU - Médebielle, Maurice
AU - Billard, Thierry
AU - Tlili, Anis
PY - 2018
DA - 2018/08/01
PB - Wiley
SP - 11781-11785
IS - 36
VL - 57
PMID - 29985549
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (до 50 авторов)
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@article{2018_Ghiazza,
author = {Clément Ghiazza and Vincent Debrauwer and Cyrille Monnereau and Lhoussain Khrouz and Maurice Médebielle and Thierry Billard and Anis Tlili},
title = {Visible‐Light‐Mediated Metal‐Free Synthesis of Trifluoromethylselenolated Arenes},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {aug},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201806165},
number = {36},
pages = {11781--11785},
doi = {10.1002/anie.201806165}
}
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MLA
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Ghiazza, Clément, et al. “Visible‐Light‐Mediated Metal‐Free Synthesis of Trifluoromethylselenolated Arenes.” Angewandte Chemie - International Edition, vol. 57, no. 36, Aug. 2018, pp. 11781-11785. https://onlinelibrary.wiley.com/doi/10.1002/anie.201806165.