Angewandte Chemie - International Edition, volume 57, issue 35, pages 11413-11417
Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals
Publication type: Journal Article
Publication date: 2018-07-30
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
An alkoxyl radical guided strategy for site‐selective functionalization of unactivated methylene and methine C−H bonds enabled by an FeII‐catalyzed redox process is described. The mild, expeditious, and modular protocol allows efficient remote aliphatic fluorination, chlorination, amination, and alkynylation of structurally and electronically varied primary, secondary, and tertiary hydroperoxides with excellent functional‐group tolerance. The application for one‐pot 1,4‐hydroxyl functionalization of non‐oxygenated alkane substrates initiated by aerobic C−H oxygenation is also demonstrated.
Top-30
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Citations by publishers
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5
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35
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45
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Wiley
45 publications, 44.12%
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American Chemical Society (ACS)
24 publications, 23.53%
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16 publications, 15.69%
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Elsevier
7 publications, 6.86%
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3 publications, 2.94%
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Thieme
2 publications, 1.96%
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Beilstein-Institut
1 publication, 0.98%
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Bentham Science
1 publication, 0.98%
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Society of Synthetic Organic Chemistry
1 publication, 0.98%
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Springer Nature
1 publication, 0.98%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.98%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Guan H. et al. Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 35. pp. 11413-11417.
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Guan H., Sun S., Mao Y., Chen L., Ran L., Huang J., Liu L. Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 35. pp. 11413-11417.
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TY - JOUR
DO - 10.1002/anie.201806434
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201806434
TI - Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals
T2 - Angewandte Chemie - International Edition
AU - Guan, Honghao
AU - Sun, Shutao
AU - Mao, Ying
AU - Huang, Jiancheng
AU - Liu, Lei
AU - Chen, Lei
AU - Ran, Lu
PY - 2018
DA - 2018/07/30 00:00:00
PB - Wiley
SP - 11413-11417
IS - 35
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
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@article{2018_Guan,
author = {Honghao Guan and Shutao Sun and Ying Mao and Jiancheng Huang and Lei Liu and Lei Chen and Lu Ran},
title = {Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {jul},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201806434},
number = {35},
pages = {11413--11417},
doi = {10.1002/anie.201806434}
}
Cite this
MLA
Copy
Guan, Honghao, et al. “Iron(II)‐Catalyzed Site‐Selective Functionalization of Unactivated C(sp3)−H Bonds Guided by Alkoxyl Radicals.” Angewandte Chemie - International Edition, vol. 57, no. 35, Jul. 2018, pp. 11413-11417. https://onlinelibrary.wiley.com/doi/10.1002/anie.201806434.