Angewandte Chemie - International Edition, volume 57, issue 39, pages 12785-12789
Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding
M. A. Kinzhalov
1, 2
,
Maria V Kashina
1, 2
,
Alexander Mikherdov
1, 2
,
Ekaterina A Mozheeva
1, 2
,
Alexander S. Novikov
1, 2
,
Mikhail S. Smirnov
1
,
Andrey S Smirnov
2
,
Daniil M Ivanov
1, 2
,
Aleksandr Yu Ivanov
1, 2
,
Sergej N Smirnov
1, 2
,
Vadim Yu. Kukushkin
1, 2, 3, 4
,
Konstantin Luzyanin
1, 2, 5, 6
Publication type: Journal Article
Publication date: 2018-08-29
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
In the current study, we evaluated the solubility of a number of organometallic species and showed that it is noticeably improved in diiodomethane when compared to other haloalkane solvents. The better solvation properties of CH2I2 were associated with the substantially better σ‐hole‐donating ability of this solvent, which results in the formation of uniquely strong solvent–(metal complex) halogen bonding. The strength of the halogen bonding is attenuated by the introduction of additional halogen atoms in the organometallic species owing to the competitive formation of more favourable intermolecular complex–complex halogen bonding. The exceptional solvation properties of diiodomethane and its inertness towards organometallic species make this solvent a good candidate for NMR studies, in particular, for the acquisition of spectra of insensitive spins.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Crystal Growth and Design
7 publications, 9.21%
|
|
|
Crystals
6 publications, 7.89%
|
|
|
CrystEngComm
6 publications, 7.89%
|
|
|
Dalton Transactions
6 publications, 7.89%
|
|
|
Russian Journal of General Chemistry
5 publications, 6.58%
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
5 publications, 6.58%
|
|
|
New Journal of Chemistry
3 publications, 3.95%
|
|
|
Chemistry - An Asian Journal
3 publications, 3.95%
|
|
|
Inorganica Chimica Acta
3 publications, 3.95%
|
|
|
Chemistry - A European Journal
3 publications, 3.95%
|
|
|
Journal of Structural Chemistry
3 publications, 3.95%
|
|
|
Inorganics
3 publications, 3.95%
|
|
|
Inorganic Chemistry
2 publications, 2.63%
|
|
|
Journal of Molecular Structure
2 publications, 2.63%
|
|
|
Russian Journal of Inorganic Chemistry
2 publications, 2.63%
|
|
|
Polyhedron
2 publications, 2.63%
|
|
|
Molecules
2 publications, 2.63%
|
|
|
Координационная химия
2 publications, 2.63%
|
|
|
Nature Communications
1 publication, 1.32%
|
|
|
European Journal of Organic Chemistry
1 publication, 1.32%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 1.32%
|
|
|
Inorganic Chemistry Frontiers
1 publication, 1.32%
|
|
|
Journal of Coordination Chemistry
1 publication, 1.32%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 1.32%
|
|
|
Coordination Chemistry Reviews
1 publication, 1.32%
|
|
|
Journal of Computational Chemistry
1 publication, 1.32%
|
|
|
Faraday Discussions
1 publication, 1.32%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
2
4
6
8
10
12
14
16
18
|
|
|
Royal Society of Chemistry (RSC)
17 publications, 22.37%
|
|
|
Pleiades Publishing
16 publications, 21.05%
|
|
|
MDPI
12 publications, 15.79%
|
|
|
Wiley
10 publications, 13.16%
|
|
|
American Chemical Society (ACS)
9 publications, 11.84%
|
|
|
Elsevier
8 publications, 10.53%
|
|
|
Springer Nature
1 publication, 1.32%
|
|
|
Taylor & Francis
1 publication, 1.32%
|
|
|
The Russian Academy of Sciences
1 publication, 1.32%
|
|
|
2
4
6
8
10
12
14
16
18
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Kinzhalov M. A. et al. Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 39. pp. 12785-12789.
GOST all authors (up to 50)
Copy
Kinzhalov M. A., Kashina M. V., Mikherdov A., Mozheeva E. A., Novikov A. S., Smirnov M. S., Smirnov A. S., Ivanov D. M., Kryukova M. A., Ivanov A. Yu., Smirnov S. N., Kukushkin V. Y., Luzyanin K. Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 39. pp. 12785-12789.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201807642
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201807642
TI - Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding
T2 - Angewandte Chemie - International Edition
AU - Mozheeva, Ekaterina A
AU - Ivanov, Aleksandr Yu
AU - Smirnov, Sergej N
AU - Kinzhalov, M. A.
AU - Kashina, Maria V
AU - Mikherdov, Alexander
AU - Novikov, Alexander S.
AU - Ivanov, Daniil M
AU - Kukushkin, Vadim Yu.
AU - Luzyanin, Konstantin
AU - Smirnov, Mikhail S.
AU - Kryukova, Mariya A
AU - Smirnov, Andrey S
PY - 2018
DA - 2018/08/29
PB - Wiley
SP - 12785-12789
IS - 39
VL - 57
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex
Copy
@article{2018_Kinzhalov,
author = {Ekaterina A Mozheeva and Aleksandr Yu Ivanov and Sergej N Smirnov and M. A. Kinzhalov and Maria V Kashina and Alexander Mikherdov and Alexander S. Novikov and Daniil M Ivanov and Vadim Yu. Kukushkin and Konstantin Luzyanin and Mikhail S. Smirnov and Mariya A Kryukova and Andrey S Smirnov},
title = {Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {aug},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201807642},
number = {39},
pages = {12785--12789},
doi = {10.1002/anie.201807642}
}
Cite this
MLA
Copy
Kinzhalov, M. A., et al. “Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding.” Angewandte Chemie - International Edition, vol. 57, no. 39, Aug. 2018, pp. 12785-12789. https://onlinelibrary.wiley.com/doi/10.1002/anie.201807642.