C−I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer
Publication type: Journal Article
Publication date: 2018-12-05
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30381881
General Chemistry
Catalysis
Abstract
While there is a growing interest in harnessing synergistic effects of more than one metal in catalysis, relatively little is known beyond bimetallic systems. This report describes the straightforward access to an air-stable Pd trimer and presents unambiguous reactivity data of its privileged capability to differentiate C-I over C-Br bonds in C-C bond formations (arylation and alkylation) of polyhalogenated arenes, which typical Pd0 and PdI -PdI catalysts fail to deliver. Experimental and computational reactivity data, including the first location of a transition state for bond activation by the trimer, are presented, supporting direct trimer reactivity to be feasible.
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57
Total citations:
57
Citations from 2024:
16
(28.07%)
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Cite this
GOST
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Diehl C. J. et al. C−I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer // Angewandte Chemie - International Edition. 2018. Vol. 58. No. 1. pp. 211-215.
GOST all authors (up to 50)
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Diehl C. J., Scattolin T., Englert U., Schoenebeck F. C−I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer // Angewandte Chemie - International Edition. 2018. Vol. 58. No. 1. pp. 211-215.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201811380
UR - https://doi.org/10.1002/anie.201811380
TI - C−I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer
T2 - Angewandte Chemie - International Edition
AU - Diehl, Claudia J
AU - Scattolin, Thomas
AU - Englert, Ulli
AU - Schoenebeck, Franziska
PY - 2018
DA - 2018/12/05
PB - Wiley
SP - 211-215
IS - 1
VL - 58
PMID - 30381881
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Diehl,
author = {Claudia J Diehl and Thomas Scattolin and Ulli Englert and Franziska Schoenebeck},
title = {C−I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {58},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.201811380},
number = {1},
pages = {211--215},
doi = {10.1002/anie.201811380}
}
Cite this
MLA
Copy
Diehl, Claudia J., et al. “C−I-Selective Cross-Coupling Enabled by a Cationic Palladium Trimer.” Angewandte Chemie - International Edition, vol. 58, no. 1, Dec. 2018, pp. 211-215. https://doi.org/10.1002/anie.201811380.