Pd‐Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction
Publication type: Journal Article
Publication date: 2019-03-19
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30811778
General Chemistry
Catalysis
Abstract
Dearomatization of anthranils with vinylcyclopropanes (VCPs) by Pd-catalyzed [4+3] cyclization reaction has been realized. In the presence of a catalytic amount of borane as an activator, bridged cyclic products were obtained in good to excellent yields with excellent stereoselectivities. By introducing a chiral PHOX ligand (L5), asymmetric dearomatization reactions of anthranils with vinylcyclopropanes proceeded with excellent enantioselectivity. Borane plays a key role for the reactivity, likely owing to the formation of a borane-anthranil complex which has been confirmed by NMR experiments.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
16
|
|
|
Organic Letters
15 publications, 13.39%
|
|
|
Organic Chemistry Frontiers
10 publications, 8.93%
|
|
|
Chemical Science
7 publications, 6.25%
|
|
|
Journal of Organic Chemistry
7 publications, 6.25%
|
|
|
Organic and Biomolecular Chemistry
7 publications, 6.25%
|
|
|
Journal of the American Chemical Society
7 publications, 6.25%
|
|
|
Angewandte Chemie - International Edition
6 publications, 5.36%
|
|
|
Chemistry - A European Journal
6 publications, 5.36%
|
|
|
Angewandte Chemie
5 publications, 4.46%
|
|
|
Advanced Synthesis and Catalysis
5 publications, 4.46%
|
|
|
ACS Catalysis
4 publications, 3.57%
|
|
|
Chemical Communications
4 publications, 3.57%
|
|
|
Asian Journal of Organic Chemistry
3 publications, 2.68%
|
|
|
Chinese Journal of Chemistry
3 publications, 2.68%
|
|
|
Green Chemistry
3 publications, 2.68%
|
|
|
Nature Synthesis
2 publications, 1.79%
|
|
|
Tetrahedron
2 publications, 1.79%
|
|
|
Chemical Reviews
2 publications, 1.79%
|
|
|
European Journal of Organic Chemistry
2 publications, 1.79%
|
|
|
Synlett
1 publication, 0.89%
|
|
|
ChemSusChem
1 publication, 0.89%
|
|
|
Chemical Society Reviews
1 publication, 0.89%
|
|
|
Advances in Catalysis
1 publication, 0.89%
|
|
|
Synthesis
1 publication, 0.89%
|
|
|
Cell Reports Physical Science
1 publication, 0.89%
|
|
|
Russian Chemical Reviews
1 publication, 0.89%
|
|
|
Molecular Catalysis
1 publication, 0.89%
|
|
|
Nature Communications
1 publication, 0.89%
|
|
|
ChemMedChem
1 publication, 0.89%
|
|
|
2
4
6
8
10
12
14
16
|
Publishers
|
5
10
15
20
25
30
35
40
|
|
|
American Chemical Society (ACS)
36 publications, 32.14%
|
|
|
Royal Society of Chemistry (RSC)
32 publications, 28.57%
|
|
|
Wiley
32 publications, 28.57%
|
|
|
Elsevier
5 publications, 4.46%
|
|
|
Springer Nature
3 publications, 2.68%
|
|
|
Georg Thieme Verlag KG
2 publications, 1.79%
|
|
|
Research Square Platform LLC
1 publication, 0.89%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.89%
|
|
|
5
10
15
20
25
30
35
40
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
112
Total citations:
112
Citations from 2024:
38
(33.93%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Cheng Q. et al. Pd‐Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 17. pp. 5739-5743.
GOST all authors (up to 50)
Copy
Cheng Q., Xie J., Weng Y. C., You S. Pd‐Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 17. pp. 5739-5743.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201901251
UR - https://doi.org/10.1002/anie.201901251
TI - Pd‐Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction
T2 - Angewandte Chemie - International Edition
AU - Cheng, Qiang
AU - Xie, Jia-Hao
AU - Weng, Yue Cheng
AU - You, Shu-Li
PY - 2019
DA - 2019/03/19
PB - Wiley
SP - 5739-5743
IS - 17
VL - 58
PMID - 30811778
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Cheng,
author = {Qiang Cheng and Jia-Hao Xie and Yue Cheng Weng and Shu-Li You},
title = {Pd‐Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201901251},
number = {17},
pages = {5739--5743},
doi = {10.1002/anie.201901251}
}
Cite this
MLA
Copy
Cheng, Qiang, et al. “Pd‐Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction.” Angewandte Chemie - International Edition, vol. 58, no. 17, Mar. 2019, pp. 5739-5743. https://doi.org/10.1002/anie.201901251.