Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis
Publication type: Journal Article
Publication date: 2019-08-05
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
31166076
General Chemistry
Catalysis
Abstract
A synergistic catalytic method combining photoredox catalysis, hydrogen-atom transfer, and proton-reduction catalysis for the dehydrogenative silylation of alkenes was developed. With this approach, a highly concise route to substituted allylsilanes has been achieved under very mild reaction conditions without using oxidants. This transformation features good to excellent yields, operational simplicity, and high atom economy. Based on control experiments, a possible reaction mechanism is proposed.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
5
10
15
20
25
|
|
|
Organic Letters
22 publications, 17.6%
|
|
|
ACS Catalysis
14 publications, 11.2%
|
|
|
Organic Chemistry Frontiers
11 publications, 8.8%
|
|
|
Chemistry - A European Journal
7 publications, 5.6%
|
|
|
Journal of Organic Chemistry
7 publications, 5.6%
|
|
|
Green Chemistry
5 publications, 4%
|
|
|
Angewandte Chemie - International Edition
4 publications, 3.2%
|
|
|
Angewandte Chemie
4 publications, 3.2%
|
|
|
Journal of the American Chemical Society
4 publications, 3.2%
|
|
|
Chemical Communications
4 publications, 3.2%
|
|
|
Chemical Science
4 publications, 3.2%
|
|
|
Organic and Biomolecular Chemistry
3 publications, 2.4%
|
|
|
Advanced Synthesis and Catalysis
3 publications, 2.4%
|
|
|
Science China Chemistry
2 publications, 1.6%
|
|
|
Chem Catalysis
2 publications, 1.6%
|
|
|
European Journal of Organic Chemistry
2 publications, 1.6%
|
|
|
Chemical Society Reviews
2 publications, 1.6%
|
|
|
Current Organic Chemistry
1 publication, 0.8%
|
|
|
Chinese Journal of Organic Chemistry
1 publication, 0.8%
|
|
|
Nature Communications
1 publication, 0.8%
|
|
|
Chinese Chemical Letters
1 publication, 0.8%
|
|
|
Nature Synthesis
1 publication, 0.8%
|
|
|
Tetrahedron Letters
1 publication, 0.8%
|
|
|
Trends in Chemistry
1 publication, 0.8%
|
|
|
ChemCatChem
1 publication, 0.8%
|
|
|
Organometallics
1 publication, 0.8%
|
|
|
ACS Organic & Inorganic Au
1 publication, 0.8%
|
|
|
Green Chemistry Letters and Reviews
1 publication, 0.8%
|
|
|
Chemical Record
1 publication, 0.8%
|
|
|
5
10
15
20
25
|
Publishers
|
10
20
30
40
50
60
|
|
|
American Chemical Society (ACS)
51 publications, 40.8%
|
|
|
Royal Society of Chemistry (RSC)
30 publications, 24%
|
|
|
Wiley
26 publications, 20.8%
|
|
|
Elsevier
9 publications, 7.2%
|
|
|
Springer Nature
4 publications, 3.2%
|
|
|
Bentham Science Publishers Ltd.
1 publication, 0.8%
|
|
|
Shanghai Institute of Organic Chemistry
1 publication, 0.8%
|
|
|
Taylor & Francis
1 publication, 0.8%
|
|
|
Oxford University Press
1 publication, 0.8%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.8%
|
|
|
10
20
30
40
50
60
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
125
Total citations:
125
Citations from 2024:
41
(32.8%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Yu W. L. et al. Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 32. pp. 10941-10945.
GOST all authors (up to 50)
Copy
Yu W. L., Luo Y. C., Yan L., Liu D., Wang Z., Xu P. F. Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 32. pp. 10941-10945.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201904707
UR - https://doi.org/10.1002/anie.201904707
TI - Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis
T2 - Angewandte Chemie - International Edition
AU - Yu, Wan Lei
AU - Luo, Yong Chun
AU - Yan, Lei
AU - Liu, Dan
AU - Wang, Zhongfu
AU - Xu, Peng Fei
PY - 2019
DA - 2019/08/05
PB - Wiley
SP - 10941-10945
IS - 32
VL - 58
PMID - 31166076
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Yu,
author = {Wan Lei Yu and Yong Chun Luo and Lei Yan and Dan Liu and Zhongfu Wang and Peng Fei Xu},
title = {Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/anie.201904707},
number = {32},
pages = {10941--10945},
doi = {10.1002/anie.201904707}
}
Cite this
MLA
Copy
Yu., Wan Lei, et al. “Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis.” Angewandte Chemie - International Edition, vol. 58, no. 32, Aug. 2019, pp. 10941-10945. https://doi.org/10.1002/anie.201904707.