Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures
Publication type: Journal Article
Publication date: 2019-08-21
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
31282122
General Chemistry
Catalysis
Abstract
A switch in time: O2 was used to switch the polymerization mechanism of a mixture of monomers from organometallic-mediated radical polymerization (OMRP) of vinyl monomers to the ring-opening copolymerization (ROCOP) of CO2/epoxides (see scheme) through unprecedented monooxygen insertion into the Co−C bond. A diblock copolymer and a poly(vinyl acetate)-b-poly(methyl acrylate)-b-polycarbonate triblock copolymer were synthesized by this one-pot strategy.
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52
Total citations:
52
Citations from 2024:
15
(28%)
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MLA
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GOST
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Zhao Y. et al. Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 40. pp. 14311-14318.
GOST all authors (up to 50)
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Zhao Y., Wang Y., Zhou X., Xue Z., Wang X., Xie X., Poli R. Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 40. pp. 14311-14318.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201906140
UR - https://doi.org/10.1002/anie.201906140
TI - Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures
T2 - Angewandte Chemie - International Edition
AU - Zhao, Yajun
AU - Wang, Yong
AU - Zhou, Xingping
AU - Xue, Zhigang
AU - Wang, Xianhong
AU - Xie, Xiaolin
AU - Poli, Rinaldo
PY - 2019
DA - 2019/08/21
PB - Wiley
SP - 14311-14318
IS - 40
VL - 58
PMID - 31282122
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Zhao,
author = {Yajun Zhao and Yong Wang and Xingping Zhou and Zhigang Xue and Xianhong Wang and Xiaolin Xie and Rinaldo Poli},
title = {Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/anie.201906140},
number = {40},
pages = {14311--14318},
doi = {10.1002/anie.201906140}
}
Cite this
MLA
Copy
Zhao, Yajun, et al. “Oxygen‐Triggered Switchable Polymerization for the One‐Pot Synthesis of CO 2 ‐Based Block Copolymers from Monomer Mixtures.” Angewandte Chemie - International Edition, vol. 58, no. 40, Aug. 2019, pp. 14311-14318. https://doi.org/10.1002/anie.201906140.