Angewandte Chemie - International Edition, volume 58, issue 39, pages 13823-13827
A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis.
Publication type: Journal Article
Publication date: 2019-09-23
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The covalent attachment of electron deficient perfluoroaryl substituents to a bis-iodotriazole pyridinium group produces a remarkably potent halogen bonding donor motif for anion recognition in aqueous media. Such a motif also establishes halogen bonding anion templation as a highly efficient method for constructing a mechanically interlocked molecule in unprecedented near quantitative yield. The resulting bis-perfluoroaryl substituted iodotriazole pyridinium axle containing halogen bonding [2]rotaxane host exhibits exceptionally strong halide binding affinities in competitive 50% water containing aqueous media, by a factor of at least three orders of magnitude greater in comparison to a hydrogen bonding rotaxane host analogue. These observations further champion and advance halogen bonding as a powerful tool for recognising anions in aqueous media.
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Citations by publishers
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35
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Wiley
34 publications, 51.52%
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14 publications, 21.21%
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3 publications, 4.55%
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3 publications, 4.55%
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Thieme
2 publications, 3.03%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.52%
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5
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15
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35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bunchuay T. et al. A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis. // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 39. pp. 13823-13827.
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Bunchuay T., Docker A., Martínez‐Martínez A., Beer P. M. A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis. // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 39. pp. 13823-13827.
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TY - JOUR
DO - 10.1002/anie.201907625
UR - https://doi.org/10.1002/anie.201907625
TI - A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis.
T2 - Angewandte Chemie - International Edition
AU - Beer, Paul M.
AU - Bunchuay, Thanthapatra
AU - Docker, Andrew
AU - Martínez‐Martínez, Aurora
PY - 2019
DA - 2019/09/23 00:00:00
PB - Wiley
SP - 13823-13827
IS - 39
VL - 58
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2019_Bunchuay,
author = {Paul M. Beer and Thanthapatra Bunchuay and Andrew Docker and Aurora Martínez‐Martínez},
title = {A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis.},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.201907625},
number = {39},
pages = {13823--13827},
doi = {10.1002/anie.201907625}
}
Cite this
MLA
Copy
Bunchuay, Thanthapatra, et al. “A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis..” Angewandte Chemie - International Edition, vol. 58, no. 39, Sep. 2019, pp. 13823-13827. https://doi.org/10.1002/anie.201907625.