Angewandte Chemie - International Edition, volume 58, issue 46, pages 16427-16432

Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte

Xiaona Li 1
Jianwen Liang 1
Ning Chen 2
Jing Luo 1
Keegan Adair 1
Changhong Wang 1
Mohammad Norouzi Banis 1, 2
Li Zhang 4
Shangqian Zhao 4
Shigang Lu 4
Huan Huang 5
Ruying Li 1
Xueliang Andy Sun 1
1
 
Department of Mechanical and Materials Engineering University of Western Ontario 1151 Richmond St London Ontario N6A 3K7 Canada
2
 
Canadian Light Source 44 Innovation Boulevard Saskatoon SK S7N 2V3 Canada
3
 
Department of Chemistry University of Western Ontario 1151 Richmond St London Ontario N6A 3K7 Canada
4
 
China Automotive Battery Research Institute Co. Ltd. 5th Floor, No. 43, Mining Building, North Sanhuan Middle Road Beijing 100088 China
5
 
Glabat Solid-State Battery Inc. 700 Collip Circle London ON N6G 4X8 Canada
Publication typeJournal Article
Publication date2019-09-30
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor16.6
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
To promote the development of solid-state batteries, polymer-, oxide-, and sulfide-based solid-state electrolytes (SSEs) have been extensively investigated. However, the disadvantages of these SSEs, such as high-temperature sintering of oxides, air instability of sulfides, and narrow electrochemical windows of polymers electrolytes, significantly hinder their practical application. Therefore, developing SSEs that have a high ionic conductivity (>10-3 S cm-1 ), good air stability, wide electrochemical window, excellent electrode interface stability, low-cost mass production is required. Herein we report a halide Li+ superionic conductor, Li3 InCl6 , that can be synthesized in water. Most importantly, the as-synthesized Li3 InCl6 shows a high ionic conductivity of 2.04×10-3 S cm-1 at 25 °C. Furthermore, the ionic conductivity can be recovered after dissolution in water. Combined with a LiNi0.8 Co0.1 Mn0.1 O2 cathode, the solid-state Li battery shows good cycling stability.

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GOST |
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GOST Copy
Li X. et al. Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 46. pp. 16427-16432.
GOST all authors (up to 50) Copy
Li X., Liang J., Chen N., Luo J., Adair K., Wang C., Norouzi Banis M., Sham T. K., Zhang L., Zhao S., Lu S., Huang H., Li R., Sun X. A. Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 46. pp. 16427-16432.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.201909805
UR - https://doi.org/10.1002/anie.201909805
TI - Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte
T2 - Angewandte Chemie - International Edition
AU - Luo, Jing
AU - Zhao, Shangqian
AU - Lu, Shigang
AU - Li, Xiaona
AU - Sun, Xueliang Andy
AU - Liang, Jianwen
AU - Chen, Ning
AU - Adair, Keegan
AU - Wang, Changhong
AU - Norouzi Banis, Mohammad
AU - Sham, Tsun Kong
AU - Zhang, Li
AU - Huang, Huan
AU - Li, Ruying
PY - 2019
DA - 2019/09/30 00:00:00
PB - Wiley
SP - 16427-16432
IS - 46
VL - 58
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex Copy
@article{2019_Li,
author = {Jing Luo and Shangqian Zhao and Shigang Lu and Xiaona Li and Xueliang Andy Sun and Jianwen Liang and Ning Chen and Keegan Adair and Changhong Wang and Mohammad Norouzi Banis and Tsun Kong Sham and Li Zhang and Huan Huang and Ruying Li},
title = {Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.201909805},
number = {46},
pages = {16427--16432},
doi = {10.1002/anie.201909805}
}
MLA
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MLA Copy
Li, Xiaona, et al. “Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte.” Angewandte Chemie - International Edition, vol. 58, no. 46, Sep. 2019, pp. 16427-16432. https://doi.org/10.1002/anie.201909805.
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