Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center
Aishabibi Kassymbek
1
,
S. F. Vyboishchikov
2, 3
,
B. Gabidullin
4
,
Denis Spasyuk
5
,
Melanie Pilkington
1
,
G. I. Nikonov
1
1
5
Canadian Light Source Inc. 44 Innovation Blvd. Saskatoon Saskatchewan S7N 2V Canada
|
Publication type: Journal Article
Publication date: 2019-12-09
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
31643119
General Chemistry
Catalysis
Abstract
In situ oxidation of the GaI compound NacNacGa by either N2 O or pyridine oxide results in the generation of a labile monomeric oxide, NacNacGa(O), which can easily cleave the C-H bonds of aliphatic and aromatic substrates featuring good donor sites. The products of this reaction are gallium organyl hydroxides. DFT calculations show that these reactions start with the formation of NacNac-Ga(O)(L) adducts, the oxo ligand of which can easily abstract protons from nearby C-H bonds, even for sp2 -hybridized carbon centers. Aliphatic amines do not enter this reaction for kinetic reasons, presumably because of the unfavorable sterics.
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30
Total citations:
30
Citations from 2025:
5
(16.67%)
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GOST
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Kassymbek A. et al. Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 50. pp. 18102-18107.
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Kassymbek A., Vyboishchikov S. F., Gabidullin B., Spasyuk D., Pilkington M., Nikonov G. I. Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 50. pp. 18102-18107.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201913028
UR - https://doi.org/10.1002/anie.201913028
TI - Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center
T2 - Angewandte Chemie - International Edition
AU - Kassymbek, Aishabibi
AU - Vyboishchikov, S. F.
AU - Gabidullin, B.
AU - Spasyuk, Denis
AU - Pilkington, Melanie
AU - Nikonov, G. I.
PY - 2019
DA - 2019/12/09
PB - Wiley
SP - 18102-18107
IS - 50
VL - 58
PMID - 31643119
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Kassymbek,
author = {Aishabibi Kassymbek and S. F. Vyboishchikov and B. Gabidullin and Denis Spasyuk and Melanie Pilkington and G. I. Nikonov},
title = {Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.201913028},
number = {50},
pages = {18102--18107},
doi = {10.1002/anie.201913028}
}
Cite this
MLA
Copy
Kassymbek, Aishabibi, et al. “Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center.” Angewandte Chemie - International Edition, vol. 58, no. 50, Dec. 2019, pp. 18102-18107. https://doi.org/10.1002/anie.201913028.