volume 59 issue 24 pages 9542-9548

An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex

Publication typeJournal Article
Publication date2020-04-01
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
Pi at last! Milling K[1,3-(SiMe3)2C3H3] (=K[A′]) with MgX2 (X=Cl, Br) produces the orange heterometallic allyl complex [K2MgA′4]. The crystal structure contains the first terminal η3-bound allyl ligand on a Mg center. Methyl methacrylate is polymerized by this complex, with activities that are comparable to K[A′] and greater than that of [{MgA′2}2].
Found 
Found 

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Koby R. F. et al. An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex // Angewandte Chemie - International Edition. 2020. Vol. 59. No. 24. pp. 9542-9548.
GOST all authors (up to 50) Copy
Koby R. F., Doerr A. M., Rightmire N. R., Schley N., Long B., Hanusa T. P. An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex // Angewandte Chemie - International Edition. 2020. Vol. 59. No. 24. pp. 9542-9548.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/anie.201916410
UR - https://doi.org/10.1002/anie.201916410
TI - An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex
T2 - Angewandte Chemie - International Edition
AU - Koby, Ross F.
AU - Doerr, Alicia M
AU - Rightmire, Nicholas R
AU - Schley, Nathan
AU - Long, B.
AU - Hanusa, Timothy P.
PY - 2020
DA - 2020/04/01
PB - Wiley
SP - 9542-9548
IS - 24
VL - 59
PMID - 32048390
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Koby,
author = {Ross F. Koby and Alicia M Doerr and Nicholas R Rightmire and Nathan Schley and B. Long and Timothy P. Hanusa},
title = {An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex},
journal = {Angewandte Chemie - International Edition},
year = {2020},
volume = {59},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201916410},
number = {24},
pages = {9542--9548},
doi = {10.1002/anie.201916410}
}
MLA
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MLA Copy
Koby, Ross F., et al. “An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex.” Angewandte Chemie - International Edition, vol. 59, no. 24, Apr. 2020, pp. 9542-9548. https://doi.org/10.1002/anie.201916410.