Angewandte Chemie - International Edition, volume 60, issue 16, pages 9003-9008

Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure

Maxim Bykov 1, 2
E. Bykova 2
I. A. Abrikosov 4
Mohammad F. Mahmood 1
Publication typeJournal Article
Publication date2021-03-10
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor16.6
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
Direct reaction between nitrogen and tantalum at approximately 100 GPa results in the energetic nitrogen-rich compounds TaN4 and TaN5, which feature N4 chains and unprecedented branched single-bonded polymeric nitrogen chains in the crystal structures, respectively. TaN5 possesses an extraordinary volumetric energy density of 18 kJ cm−3, exceeding well-known high-energy-density materials.

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GOST Copy
Bykov M. et al. Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 16. pp. 9003-9008.
GOST all authors (up to 50) Copy
Bykov M., Bykova E., Ponomareva A., Abrikosov I. A., Chariton S., Prakapenka V., Mahmood M. F., Dubrovinsky L., Goncharov A. Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 16. pp. 9003-9008.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.202100283
UR - https://doi.org/10.1002/anie.202100283
TI - Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure
T2 - Angewandte Chemie - International Edition
AU - Mahmood, Mohammad F.
AU - Bykov, Maxim
AU - Bykova, E.
AU - Ponomareva, A.V.
AU - Abrikosov, I. A.
AU - Chariton, Stella
AU - Prakapenka, V.
AU - Dubrovinsky, L.
AU - Goncharov, Alexander
PY - 2021
DA - 2021/03/10 00:00:00
PB - Wiley
SP - 9003-9008
IS - 16
VL - 60
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex Copy
@article{2021_Bykov,
author = {Mohammad F. Mahmood and Maxim Bykov and E. Bykova and A.V. Ponomareva and I. A. Abrikosov and Stella Chariton and V. Prakapenka and L. Dubrovinsky and Alexander Goncharov},
title = {Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure},
journal = {Angewandte Chemie - International Edition},
year = {2021},
volume = {60},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.202100283},
number = {16},
pages = {9003--9008},
doi = {10.1002/anie.202100283}
}
MLA
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MLA Copy
Bykov, Maxim, et al. “Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure.” Angewandte Chemie - International Edition, vol. 60, no. 16, Mar. 2021, pp. 9003-9008. https://doi.org/10.1002/anie.202100283.
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