Angewandte Chemie - International Edition, volume 60, issue 16, pages 9003-9008
Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure
Maxim Bykov
1, 2
,
E. Bykova
2
,
A.V. Ponomareva
3
,
I. A. Abrikosov
4
,
Stella Chariton
5
,
V. Prakapenka
5
,
Mohammad F. Mahmood
1
,
L. Dubrovinsky
6
,
2
The Earth and Planets Laboratory Carnegie Institution for Science Washington DC 20015 USA
|
6
Bayerisches Geoinstitut 95447 Bayreuth Germany
|
Publication type: Journal Article
Publication date: 2021-03-10
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Direct reaction between nitrogen and tantalum at approximately 100 GPa results in the energetic nitrogen-rich compounds TaN4 and TaN5, which feature N4 chains and unprecedented branched single-bonded polymeric nitrogen chains in the crystal structures, respectively. TaN5 possesses an extraordinary volumetric energy density of 18 kJ cm−3, exceeding well-known high-energy-density materials.
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Bykov M. et al. Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 16. pp. 9003-9008.
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Bykov M., Bykova E., Ponomareva A., Abrikosov I. A., Chariton S., Prakapenka V., Mahmood M. F., Dubrovinsky L., Goncharov A. Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 16. pp. 9003-9008.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.202100283
UR - https://doi.org/10.1002/anie.202100283
TI - Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure
T2 - Angewandte Chemie - International Edition
AU - Mahmood, Mohammad F.
AU - Bykov, Maxim
AU - Bykova, E.
AU - Ponomareva, A.V.
AU - Abrikosov, I. A.
AU - Chariton, Stella
AU - Prakapenka, V.
AU - Dubrovinsky, L.
AU - Goncharov, Alexander
PY - 2021
DA - 2021/03/10
PB - Wiley
SP - 9003-9008
IS - 16
VL - 60
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2021_Bykov,
author = {Mohammad F. Mahmood and Maxim Bykov and E. Bykova and A.V. Ponomareva and I. A. Abrikosov and Stella Chariton and V. Prakapenka and L. Dubrovinsky and Alexander Goncharov},
title = {Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure},
journal = {Angewandte Chemie - International Edition},
year = {2021},
volume = {60},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.202100283},
number = {16},
pages = {9003--9008},
doi = {10.1002/anie.202100283}
}
Cite this
MLA
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Bykov, Maxim, et al. “Stabilization of Polynitrogen Anions in Tantalum–Nitrogen Compounds at High Pressure.” Angewandte Chemie - International Edition, vol. 60, no. 16, Mar. 2021, pp. 9003-9008. https://doi.org/10.1002/anie.202100283.