Angewandte Chemie - International Edition

, volume 60 , issue 17 , pages 9650-9659

Lewis Acid Strength of Interfacial Metal Sites Drives CH ₃ OH Selectivity and Formation Rates on Cu‐Based CO ₂ Hydrogenation Catalysts

Gina Noh ¹

Erwin Lam ¹

Daniel T Bregante ²

Jordan Meyet ¹

Petr Šot ¹

David H. Flaherty ²

Christophe Copéret ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry and Applied Biosciences ETH Zürich Vladimir Prelog Weg 1–5 8093 Zürich Switzerland |

Department of Chemical and Biomolecular Engineering University of Illinois at Urbana-Champaign Urbana IL 61801 USA |

Publication type: Journal Article

Publication date: 2021-03-18

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202100672

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PubMed ID: 33559910

General Chemistry

Catalysis

Abstract

Cu nanoparticles, dispersed on supports decorated with isolated group IV and V metal centers on SiO2, catalyze the selective hydrogenation of CO2 to CH3OH. The promotion of CH3OH formation rates and selectivity correlates with the Lewis acid strength of the group IV and V dopants, which stabilize surface intermediates at the periphery of Cu nanoparticles.

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Noh G. et al. Lewis Acid Strength of Interfacial Metal Sites Drives CH 3 OH Selectivity and Formation Rates on Cu‐Based CO 2 Hydrogenation Catalysts // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 17. pp. 9650-9659.

GOST all authors (up to 50) Copy

Noh G., Lam E., Bregante D. T., Meyet J., Šot P., Flaherty D. H., Copéret C. Lewis Acid Strength of Interfacial Metal Sites Drives CH 3 OH Selectivity and Formation Rates on Cu‐Based CO 2 Hydrogenation Catalysts // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 17. pp. 9650-9659.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/anie.202100672

UR - https://doi.org/10.1002/anie.202100672

TI - Lewis Acid Strength of Interfacial Metal Sites Drives CH 3 OH Selectivity and Formation Rates on Cu‐Based CO 2 Hydrogenation Catalysts

T2 - Angewandte Chemie - International Edition

AU - Noh, Gina

AU - Lam, Erwin

AU - Bregante, Daniel T

AU - Meyet, Jordan

AU - Šot, Petr

AU - Flaherty, David H.

AU - Copéret, Christophe

PY - 2021

DA - 2021/03/18

PB - Wiley

SP - 9650-9659

IS - 17

VL - 60

PMID - 33559910

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Noh,

author = {Gina Noh and Erwin Lam and Daniel T Bregante and Jordan Meyet and Petr Šot and David H. Flaherty and Christophe Copéret},

title = {Lewis Acid Strength of Interfacial Metal Sites Drives CH 3 OH Selectivity and Formation Rates on Cu‐Based CO 2 Hydrogenation Catalysts},

journal = {Angewandte Chemie - International Edition},

year = {2021},

volume = {60},

publisher = {Wiley},

month = {mar},

url = {https://doi.org/10.1002/anie.202100672},

number = {17},

pages = {9650--9659},

doi = {10.1002/anie.202100672}

}

MLA

Cite this

MLA Copy

Noh, Gina, et al. “Lewis Acid Strength of Interfacial Metal Sites Drives CH 3 OH Selectivity and Formation Rates on Cu‐Based CO 2 Hydrogenation Catalysts.” Angewandte Chemie - International Edition, vol. 60, no. 17, Mar. 2021, pp. 9650-9659. https://doi.org/10.1002/anie.202100672.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)