volume 60 issue 31 pages 17211-17217

Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange

Publication typeJournal Article
Publication date2021-06-26
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
An efficient and broadly applicable palladium-catalyzed iodination of inexpensive and abundant aryl and vinyl carboxylic acids via in situ activation to the acid chloride and formation of a phosphonium salt was developed. The use of 1-iodobutane as iodide source in combination with a base and a deoxychlorinating reagent gives access to a wide range of aryl and vinyl iodides under Pd/Xantphos catalysis.
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GOST Copy
Boehm P. et al. Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 31. pp. 17211-17217.
GOST all authors (up to 50) Copy
Boehm P., Martini T., Lee Y. H., Cacherat B., Morandi B. Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 31. pp. 17211-17217.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.202103269
UR - https://doi.org/10.1002/anie.202103269
TI - Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange
T2 - Angewandte Chemie - International Edition
AU - Boehm, Philip
AU - Martini, Tristano
AU - Lee, Yong Ho
AU - Cacherat, Bastien
AU - Morandi, Bill
PY - 2021
DA - 2021/06/26
PB - Wiley
SP - 17211-17217
IS - 31
VL - 60
PMID - 34013616
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Boehm,
author = {Philip Boehm and Tristano Martini and Yong Ho Lee and Bastien Cacherat and Bill Morandi},
title = {Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange},
journal = {Angewandte Chemie - International Edition},
year = {2021},
volume = {60},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/anie.202103269},
number = {31},
pages = {17211--17217},
doi = {10.1002/anie.202103269}
}
MLA
Cite this
MLA Copy
Boehm, Philip, et al. “Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange.” Angewandte Chemie - International Edition, vol. 60, no. 31, Jun. 2021, pp. 17211-17217. https://doi.org/10.1002/anie.202103269.